SpringerOpen Newsletter

Receive periodic news and updates relating to SpringerOpen.

Open Access Highly Accessed Open Badges Nano Express

Effect of physisorption and chemisorption of water on resonant modes of rolled-up tubular microcavities

Jian Zhong12, Jiao Wang2, Gaoshan Huang2, Guoliang Yuan1* and Yongfeng Mei2*

Author Affiliations

1 Department of Materials Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, People’s Republic of China

2 Department of Materials Science, Fudan University, Shanghai 200433, People’s Republic of China

For all author emails, please log on.

Nanoscale Research Letters 2013, 8:531  doi:10.1186/1556-276X-8-531

Published: 18 December 2013


Both blue- and redshifts of resonant modes are observed in the rolled-up Y2O3/ZrO2 tubular microcavity during a conformal oxide coating process. Our investigation based on spectral analyses suggests that there are two competitive processes during coating: desorption of both chemically and physically absorbed water molecules and increase of the tube wall thickness. The redshift is due to the increase of the wall thickness and corresponding light confinement enhancement. On the other hand, desorption of water molecules by heating leads to a blueshift. The balance of these two factors produces the observed bi-directional shift of the modes while they both contribute to promoted quality factor after coating.

Microcavity; Coating; Mode shift; Desorption; Detection