Table 1

Polycondensation of TSH and Zn(OAc)2
Run Monomer Yield (%)a Mn (Mw/Mn)b Zn/Sc
1 OTSH 48 7400 (1.4) 0.29
2 BTSH 64 -d 0.40
3 HTSH, 62 -d 0.37
4 IATSH 68 -d 0.45
5 EHTSH 62 -d 0.71

Conditions: TSH 0.200 mmol, Zn(OAc)2 0.300 mmol, dioxane 5.0 mL, 60°C, 24 h, N2. aIsolated yield after precipitation with methanol. bEstimated by GPC (THF, polystyrene standard). cEstimated using EDX (ratios calculated as averages of ten spots). dNot measurable due to poor solubility.

Ochiai and Konta

Ochiai and Konta Nanoscale Research Letters 2013 8:373   doi:10.1186/1556-276X-8-373

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