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In situ preparation of monodispersed Ag/polyaniline/Fe3O4 nanoparticles via heterogeneous nucleation

Longchun Bian1, Lixia Bao2, Jiliang Wang12* and Jingxin Lei2

Author Affiliations

1 School of Chemical Science and Technology, Yunnan University, Kunming 650091, People's Republic of China

2 State Key Laboratory of Polymer Materials Engineering, Polymer Research Institute of Sichuan University, Chengdu 610065, People's Republic of China

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Nanoscale Research Letters 2013, 8:309  doi:10.1186/1556-276X-8-309

Published: 3 July 2013


Acrylic acid and styrene were polymerized onto monodispersed Fe3O4 nanoparticles using a grafting copolymerization method. Aniline molecules were then bonded onto the Fe3O4 nanoparticles by electrostatic self-assembly and further polymerized to obtain uniform polyaniline/Fe3O4 (PANI/Fe3O4) nanoparticles (approximately 35 nm). Finally, monodispersed Ag/PANI/Fe3O4 nanoparticles were prepared by an in situ reduction reaction between emeraldine PANI and silver nitrate. Fourier transform infrared and UV-visible spectrometers and a transmission electron microscope were used to characterize both the chemical structure and the morphology of the resulting nanoparticles.

Nanoparticles; Ferromagnetic; In situ composites; Polyaniline; Self-assembly