Additional file 4: Figure S4.
Control experiments on glassy carbon to rule out redox current. (A) Cyclic voltammetry scan on glassy carbon in 2-mM ferricyanide solution and 2-mM ferricyanide solution with 0.5 M KCl. (B) Cyclic voltammetry scan on glassy carbon in 50-mM ferricyanide solution and 25-mM ferricyanide/ferricyanide solution (cyclic voltammetry scan from −0.6 to +0.6 V. Reference/counter electrode, Ag/AgCl; working electrode, glassy carbon). With the supporting electrolyte KCl, oxidation and reduction peaks were observed at 0.29 and 0.06 V, respectively. However, no redox peaks were found without KCl, which supports that no redox reaction occurred in the solution.
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Zhan et al. Nanoscale Research Letters 2013 8:279 doi:10.1186/1556-276X-8-279