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Impact of N on the atomic-scale Sb distribution in quaternary GaAsSbN-capped InAs quantum dots

Daniel F Reyes1*, David González1, Jose M Ulloa2, David L Sales1, Lara Dominguez1, Alvaro Mayoral3 and Adrian Hierro2

Author affiliations

1 Departamento de Ciencia de los Materiales e IM y QI, Universidad de Cádiz, Puerto Real, Cádiz, 11510, Spain

2 Institute for Systems based on Optoelectronics and Microtechnology (ISOM) and Departamento Ingenieria Electronica, Universidad Politecnica de Madrid, Ciudad Universitaria s/n, Madrid, 28040, Spain

3 Laboratorio de Microscopías Avanzadas (LMA), Instituto de Nanociencia de Aragón(INA), Universidad de Zaragoza, Mariano Esquillor, Edificio I+D, Zaragoza, 50018, Spain

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Citation and License

Nanoscale Research Letters 2012, 7:653  doi:10.1186/1556-276X-7-653

The electronic version of this article is the complete one and can be found online at: http://www.nanoscalereslett.com/content/7/1/653


Received:2 November 2012
Accepted:13 November 2012
Published:27 November 2012

© 2012 Reyes et al.; licensee Springer.

This is an Open Access article distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

The use of GaAsSbN capping layers on InAs/GaAs quantum dots (QDs) has recently been proposed for micro- and optoelectronic applications for their ability to independently tailor electron and hole confinement potentials. However, there is a lack of knowledge about the structural and compositional changes associated with the process of simultaneous Sb and N incorporation. In the present work, we have characterized using transmission electron microscopy techniques the effects of adding N in the GaAsSb/InAs/GaAs QD system. Firstly, strain maps of the regions away from the InAs QDs had revealed a huge reduction of the strain fields with the N incorporation but a higher inhomogeneity, which points to a composition modulation enhancement with the presence of Sb-rich and Sb-poor regions in the range of a few nanometers. On the other hand, the average strain in the QDs and surroundings is also similar in both cases. It could be explained by the accumulation of Sb above the QDs, compensating the tensile strain induced by the N incorporation together with an In-Ga intermixing inhibition. Indeed, compositional maps of column resolution from aberration-corrected Z-contrast images confirmed that the addition of N enhances the preferential deposition of Sb above the InAs QD, giving rise to an undulation of the growth front. As an outcome, the strong redshift in the photoluminescence spectrum of the GaAsSbN sample cannot be attributed only to the N-related reduction of the conduction band offset but also to an enhancement of the effect of Sb on the QD band structure.

Keywords:
III-V quantum dots, GaAsSb; N incorporation; Sb distribution, Strain state; 73.21.La quantum dots; 78.55.Cr III-V semiconductors; 68.55.Ln defects and impurities: doping, implantation, distribution, concentration, etc.; 68.55.Nq composition and phase identification

Background

A noteworthy effort has been made over the last years to broaden the emission wavelength of InAs/GaAs quantum dot (QD) lasers towards 1.55 μm, i.e., the telecommunication band which better matches the transmission characteristics of optical fibers, providing higher data rates at longer distances. The utilization of different types of capping layers (CL), such as strain-reducing layers (SRL) [1,2] or strain-compensating layers (SCL) [3], has been widely used to directly cover this issue by modifying the strain state of the QDs. Special attention has been paid to GaAsSb SRLs to take advantage of the surfactant role of Sb, which suppresses the defect generation and QD decomposition [4,5]. Additionally, GaAsSb capping layers present an extra degree of freedom as the emission band alignment changes from type I to type II at a certain Sb content [6]. A step forward is the addition of N in the CL to form a GaNAsSb quaternary system, which has been very recently realized [7]. As N reduces only the conduction band (CB) of GaAs and Sb rises the valence band (VB) of GaAs, the quaternary alloy GaAsSbN used as a CL for InAs/GaAs QDs allows independent tailoring of the electron and hole confinement potentials in a wide range, which could be useful for many applications [7].

However, there is a lack of knowledge about the structural and compositional changes associated with the process of simultaneous Sb and N incorporation. On one hand, the difficulty of incorporating antimony inside GaAs structures has repeatedly been reported in literature [8]. Indeed, the interdiffusion effects that affect the relative composition of In/Ga and As/Sb in and around the QD islands are still debated [9,10]. On the other hand, arising from specific properties of N such as its large electronegativity and small atomic volume, it is well known that dilute nitride alloys create statistically large compositional fluctuations [11].

The aim of this work is to describe, by advanced transmission electron microscopy (TEM) techniques, the atomic distribution in InAs QD capped by GaAsSb SRL with and without N and its effect on the photoluminescence spectra. The strain in the regions close and away from the InAs QDs is analyzed, allowing the estimation of the compositional distribution of the SRL and nanostructures. Moreover, we have qualitatively extracted chemical information from aberration-corrected Z-contrast images by calculation of integrated intensities of the atomic columns [12]. Our results reveal that the incorporation of N induces significant changes in the Sb distribution in the InAs/GaAsSb QD system.

Methods

Equipment and techniques

Two samples (S-Sb and S-SbN) were grown by solid-source molecular beam epitaxy on Si-doped (100) n+ GaAs substrates. The QDs in both samples were grown by depositing 2.7 monolayers (ML) of InAs at 450°C and 0.04 ML/s on an intrinsic GaAs buffer layer. A nominally 5.0-nm-thick GaAs0.88Sb0.12 layer grown at 470°C was used to cover the QDs in sample S-Sb, followed by 250 nm of GaAs. Sample S-SbN was identical, but a nominal 2% N content was added to the 5.0-nm-thick CL. This active N was generated from a radio frequency (RF) plasma source with a 0.1-sccm flow of pure N2 (6 N) and a RF power of 60 W. The photoluminescence (PL) was measured at 15 K using a closed-cycle helium cryostat and a He-Ne laser as the excitation source. The emitted light was dispersed through a 1-m spectrometer and detected with a liquid nitrogen-cooled Ge detector using standard lock-in techniques. Conventional transmission electron microscopy (CTEM) and high-resolution TEM (HRTEM) were carried out in a JEOL 2011 LaB6 filament microscope (JEOL Ltd., Akishima, Tokyo, Japan) operating at 200 kV and by Z-contrast imaging using a high-angle annular dark field (HAADF) detector in a JEOL 2010 FEG microscope working at 200 kV in scanning TEM (STEM) mode. Additionally, high-resolution STEM (HRSTEM) studies were performed using X-FEG FEI Titan microscope (FEI, Hillsboro, OR, USA) at 300 kV. This last microscope is equipped with a spherical aberration (Cs) corrector for the electron probe (CEOS company, Heidelberg, Germany), allowing a probe size of 0.08 nm (mean size).

Strain analysis

Maps of the strain along the growth direction (εzz) were determined from HRTEM images acquired on the [110] pole axis using the geometrical phase analysis (GPA). The GPA is based on the calculation of the displacement field and subsequently the strain map by numerical derivatives, from the phase images for different and non-collinear vectors. A full description of the methodology can be found elsewhere [13]. The tensile strain along the (001) direction, εzz, due to the tetragonal distortion in pseudomorphic samples under biaxial stress could be used to determine the in-plane strain εxx through the biaxial strain coefficient, RB = −εzz/εxx, which in the case of cubic materials is equal to RB = 2C12/C11, with Cij being the Voigt values stiffness tensor. As GaAs and GaSb have the same biaxial strain coefficient (RB = 0.899), the measurement of εxx allows us an assessment of the composition, assuming a compliance with Vegard's law at these contents.

High-resolution Z-contrast analysis

The used method is based on the analysis of normalized integrated intensities (R) of high-resolution aberration-corrected Z-contrast images. The R values are calculated as the quotient of the integrated intensity around the cationic and anionic columns with respect to a binary compound (the substrate), which is chosen as a reference [12]. In our case, InAs QDs in GaAsSb(N) is a suitable system for Z-contrast analysis due to the difference in the atomic number of Sb (ZSb=51) with respect to As (ZAs=33), and In (ZIn=49) with respect to Ga (ZGa=31), and their almost linear dependency on the composition [9]. Firstly, local intensity maxima of each dumbbell are located by applying the peak detection tool of the Peak Pairs Analysis software [14]. Secondly, intensities from pixels corresponding to the cationic (In+Ga) and anionic (As+Sb) columns are integrated from the raw (unfiltered) image. From this point, we assume that the chemical information extracted from a single atomic column is weakly affected by the neighboring ones when using a sub-angstrom electron probe, and therefore, the signal is essentially related to the composition of the selected atomic column. In this case, two integrated intensity quotients (Ri) were determined for every dumbbell in the image: R1, as the ratio between the integrated intensity in the anionic As/Sb column and the averaged integrated intensity of the As columns in the GaAs substrate within the same image; and R2 as the ratio between the integrated intensity in the cationic Ga/In column and the average integrated intensity of the Ga column in the GaAs region. The results of the Ri values are plotted over the HRSTEM image using a color scale where the reddest values are associated with a higher proportion of heavier elements, and the bluest, the contrary.

Results and discussion

Figure 1 shows the 15-K PL spectra of both samples. Adding N induced a redshift of 80 meV, but it also significantly increased the full width at half maximum (FWHM) and reduced the integrated intensity by a factor of 12. Although the large redshift can be partially explained by the reduced QD-barrier conduction band offset in the presence of N [7], nitrogen should also decrease the SRL redshift effect, the strong differences in the PL lineshape and intensity point to the presence of N-induced structural changes. In order to elucidate the possible reasons of this behavior, the samples were analyzed by transmission electron microscopy techniques to determine the strain fields and compositional distribution.

thumbnailFigure 1. 15-K PL spectra of the two InAs/GaAs QD layers capped with GaAsSb and GaAsSbN. The nominal Sb content is the same in both samples. The nominal N content in S-SbN is 2%.

From CTEM analysis, no extended defects such as dislocations or planar defects were found in either of the samples (<108 cm−2), denoting that the degradation of the PL efficiency by the addition of N should not be attributed to these kinds of defects. In Figure 2a,b, low-magnification HAADF-STEM images show representative views of samples S-Sb and S-SbN, respectively. In these Z-contrast images, regions with higher content of heavy elements appear brighter, thus making possible a clear distinction between the position and shape of the QDs and the CL surrounded by GaAs. After analyzing 75 QDs, the average QD base and height were measured as 13 ± 2 nm and 3.4 ± 0.6 nm in both samples, and no appreciable differences in the QD size are observed within the statistical error. The addition of N to the GaAsSb CL does not seem to influence the structure of the QD itself. However, this was not exactly the case for the CL. It should be noted that the CL in the region between QDs was thicker in the S-Sb sample (8.7 nm) than in the S-SbN (7.2 nm). Furthermore, sample S-Sb shows a planar top interface of the CL even when it wraps up the QD, that is to say, the CL over the QDs is thinner than in between QDs. A strong Sb segregation in the growth direction was observed in areas between QDs. By contrast, the CL of the S-SbN sample is adapted to the wetting layer QD surface, trying to keep the thickness constant, and therefore causing a growth front undulation when it covers the QDs. This is the first clue that the combination of N and Sb in the capping layer does not only lead to a band offset and a strain modification effect but also has a strong effect on the morphology of the structure.

thumbnailFigure 2. HAADF images of samples (a) S-Sb and (b) S-SbN acquired at low magnification. Dark solid arrows mark the QDs position, and dashed arrows in (b) show the GaAsSbN lobules formed over the QDs.

In order to evaluate the strain in the CL, HRTEM images were acquired on the [110] zone axis far from any QD (Figure 3a,b) and processed to obtain strain maps using GPA [13]. From the measurement of εzz and assuming the compliance with Vegard's law at these contents, the Sb composition in the CL of sample S-Sb was estimated. Thus, in the CL regions between QDs for sample S-Sb (Figure 3c), the average strain measured, εzz = 1.5 ± 0.2%, corresponds with a Sb content of 10.3 ± 0.4%, close to the designed value of 12%. In contrast, a reduced εzz = 0.6 ± 0.1% was observed in comparable areas of the S-SbN sample (Figure 3d). This large reduction needs to be attributed to N incorporation, which rises to 2.6 ± 0.4% (in reasonable agreement with the nominal composition of 2%). In addition, as is observed in Figure 3d, the strain distribution in the CL of the S-SbN sample becomes more inhomogeneous, which points to a composition modulation with the presence of Sb-rich and Sb-poor regions in the range of a few nanometers. Certainly, the addition of N enhances even more the large miscibility gap of GaAsSb [15] and gives rise to strong composition fluctuations. The observed clusters can act as traps for carrier, reducing the injection efficiency in the InAs QDs. The presence of the N-induced non-radiative centers (characteristic in N-diluted alloys) [16] together with the higher compositional inhomogeneities is a possible explanation for the degradation of the PL.

thumbnailFigure 3. HRTEM images and strain maps of CLs. The images were acquired along the [110] zone axis of the CLs in the samples (a) S-Sb and (b) S-SbN, and (c,d) their strain maps, respectively. Color scales of the strain are shown on the right.

However, the situation changes in and around the QDs. Figure 4 shows the HRTEM and strain maps of QDs from both samples. Firstly, the average strain εzz evaluated within the core of up to five QDs of the S-Sb sample was 3.8 ± 0.2%, which is very similar to the average strain of 3.5 ± 0.2% measured in several QDs in S-SbN. Secondly, the average strain in the CL region above the QDs was also similar in both cases, with the εzz being 1.3 ± 0.2% and 1.5 ± 0.2% for the S-Sb and S-SbN samples, respectively. Important conclusions can be extracted from the strain data. The marked strain release in the CL between QDs when adding N (εzz lowers from 1.5% to 0.6% as mentioned in the previous paragraph) should entail a decrease in εzz inside the QD due to the reduced SRL effect [17]. This did not happen, and the explanation of the observed result implies that the CL must undergo clear changes in the surroundings of the QDs. Assuming a homogenous distribution of N over the CL in S-SbN, the measured strain implies that the Sb content in that region must be approximately 17%, which indicates a strong Sb migration towards the top of the QDs in the S-SbN sample. This assumption of a homogeneous N distribution is in agreement with the results of Ciatto et al. [18], who found that the Sb local environment is essentially random and that no significant preferential Sb-N pairing occurs over random statistics. The higher Sb content on top of the QDs compensates the counteracting effect of N on the strain reduction effect of the CL, explaining the similar strain values also observed inside the QDs. It seems that the system rearranges itself through composition modulation in the CL in order to keep the total strain in the QD region constant and equal to what would likely be the most stable value.

thumbnailFigure 4. HRTEM images and strain maps of QDs. The images were acquired along the [110] zone axis of the QDs in the samples (a) S-Sb and (b) S-SbN, and (c,d) their strain maps, respectively. Color scales of the strain are shown on the right.

To confirm our hypothesis about the chemical composition in and around the QDs, HRSTEM Z-contrast imaging was carried out for both samples (Figure 5a,d). Anion and cation sub-nets are resolved in these images, showing the characteristic ‘dumbbells’ found at the [110] zone axis orientation. Figure 5g shows a magnified dumbbell where the upper and lower columns are the anionic and cationic components, respectively. In order to estimate column-by-column the Sb and In contents, a method similar to the one used in [9,19] was performed. The R values corresponding to each sub-net column, Ri, are represented in Figure 5 with colored dots, where higher values (red dots) are associated with atomic columns with higher proportion of heavier elements with respect to the corresponding atomic columns in GaAs. It is assumed in this work that the minimum Ri measured in each image corresponds to a pure Ga or As column, respectively. Taking all this into account, Figure 5b,e depicts the estimated In/Ga distribution of both samples. Red dots, related to In-rich atomic columns, perfectly draw the QD and wetting layer (WL) regions. No appreciable out-diffused In from the QD was evinced. Still, in the case of the anionic positions, the panorama is very different when comparing the two samples. The redder dots in Figure 5c,f are associated to anionic columns with a higher content of Sb. As it is shown in Figure 5c for the S-Sb sample, the Sb atoms are mainly segregated to the upper region of the CL, leading to a Sb-poor region just above the WL. This is in agreement with previous results from scanning tunneling microscopy [5,20], which reported that a region depleted of both Sb and In is distinguishable at the WL-CL and QD-CL interfaces. This kind of behavior - the accumulation of Sb atoms on the growth-front surface - has been reported in many III-V systems [21,22], and it is a consequence of the bond energy differences. Since the Ga-Sb bond is considerably weaker than the Ga-As one, there is a preference for Sb atoms to be expelled to the surface [23]. Moreover, the Sb concentration in the CL of the S-Sb sample was not excessively altered by the presence of QDs. This could explain the lack of undulation on the growth front observed in the capping layer above the QD. Nevertheless, the Sb distribution intensely changes in the case of sample S-SbN (Figure 5f). In this case, the reddest dots were located on and around the QDs in a higher density than in sample S-Sb. The higher Sb content around the QDs agrees with the higher εzz values determined in the strain maps on the QD with respect to the CL regions in between the QDs that pointed to a lateral migration of Sb towards the QDs.

thumbnailFigure 5. HR Z-contrast images of QDs and their integrated intensity (compostition related) maps. The images were acquired along the [110] zone axis of samples (a) S-Sb and (d) S-SbN, and their respective maps of the R values (Ri) of (b,e) cations and (c,f) anions. Higher values (hot colors) can be attributed to atomic columns with heavier elements, In or Sb, respectively. (g) The regions used for intensity integration over each atomic column.

Certainly, the presence of N (with Z = 7) should give rise to a small decrease of the anionic R1 quotient. However, the number of anionic columns with R1 > 1 in S-SbN amply exceeds the observed ones in sample S-Sb. In this sense, statistical analysis in dilute nitrides of GaAsN had shown that the incorporation of N at low contents causes negligible changes in the brightness of the atomic columns but a strong increase in the valleys between them [24]. This fact does not affect our measurements since the pixels selected to calculate the R quotients just avoid the area between atomic columns [9]. However, the impossibility to detect the position and content of N around the QD, together with the non-negligible influence of static atomic displacements in the Z-signal, disables any attempt to quantify the Sb concentration in sample S-SbN by this technique [25].

All these results indicate that the addition of N to the GaAsSb capping layer increases the amount of Sb on top and around the QDs, inducing an undulation in the capping layer which tends to adapt to the morphology of the QD below it. Though this migration leads to an enrichment of Sb around the QDs, the strain-compensating effect of N gives rise to similar strain fields around and inside of the S-SbN QDs to those for the S-Sb ones. When the CL covers a QD, nitrogen fosters the Sb to accumulate on top of the partially relaxed InAs QDs since GaSb has a very similar lattice constant with InAs. On the other hand, as the composition threshold for the total restraint of GaAsSb/InAs QD dissolution in the capping process is around 11% to 14% of Sb [26,27], we could assume that the dissolution process of InAs QDs during the capping growth is completely suppressed for both samples and that the In atoms are not being relocated from the top of the QDs to the QD base [1,7,28]. This explains why no significant differences in the size and morphology of the QDs are seen in both samples. The addition of N greatly enhances the lateral Sb segregation, and this fact could even induce to a transition to a type II band alignment in the VB, which is expected for Sb contents of 14% to 17% [1,28]. Further work is in progress to clarify this issue.

Conclusions

In summary, we have presented PL results and compositional distribution analysis of two InAs/GaAs QD samples capped by GaAsSb SRL with and without N incorporation. First, the addition of N produces a long redshift in the PL spectra, but it also reduces its efficiency by increasing the FWHM and reducing the intensity. However, the TEM results show that the PL behavior is not due to modifications in the QD sizes or to an increase in the extended defect density. On the other hand, the deformation analysis displays important changes in the nanostructure when N is added: (1) a large strain reduction in the CL regions away from the QDs and (2) an enhancement of the miscibility gap that gives rise to strong composition fluctuations and reduces the carrier injection efficiency in the InAs QDs. On the contrary, the average strain within the core of QDs and in the CL region above the QDs was also similar in both cases, which suggests a strong Sb migration towards the top of the QDs in the S-SbN sample (approximately 17%). Certainly, compositional maps of column resolution from aberration-corrected HAADF HRSTEM images corroborated the preferential deposition of Sb above the InAs QD together with an undulation of the growth front by the addition of N. Together with the reduction of the CB offset by the N incorporation, an additional redshift is induced due to a Sb accumulation on top of the QDs. Therefore, the N implementation could boost the features of GaAsSb capping layers on InAs QDs since it multiplies the Sb content around the QDs.

Competing interests

The authors declare that they have no competing interests.

Authors’ contributions

JMU and AH designed and grew the samples and carried out the PL study. DFR acquired TEM data and carried out the analysis of results. LD prepared the TEM samples and, together with AM, collaborated in the TEM data acquisition. DG and DS designed the TEM studies and supervised the TEM analysis. All authors actively discussed the results and participated on drafting the manuscript, and they all read and approved the final one.

Acknowledgments

This work has been supported by MICINN (Project No. MAT2010-15206), CAM (Project Nos. P2009/ESP-1503 and CCG10-UPM/TIC-4932), JA (Project No. P09-TEP-5403), and by the EU (COST Action MP0805). J. M. Ulloa was supported by MICINN through the ‘Ramón y Cajal’ program.

References

  1. Liu HY, Steer MJ, Badcock TJ, Mowbray DJ, Skolnick MS, Navaretti P, Groom KM, Hopkinson M, Hogg RA: Long-wavelength light emission and lasing from InAsGaAs quantum dots covered by a GaAsSb strain-reducing layer.

    Appl Phys Lett 2005, 86:143108. Publisher Full Text OpenURL

  2. Yeh NT, Nee TE, Chyi JI, Hsu TM, Huang CC: Matrix dependence of strain-induced wavelength shift in self-assembled InAs quantum-dot heterostructures.

    Appl Phys Lett 2000, 76:1567-1569. Publisher Full Text OpenURL

  3. Zhang XQ, Ganapathy S, Kumano H, Uesugi K, Suemune I: Photoluminescence study of InAs quantum dots embedded in GaNAs strain compensating layer grown by metalorganic-molecular-beam epitaxy.

    J Appl Phys 2002, 92:6813-6818. Publisher Full Text OpenURL

  4. Akahane K, Yamamoto N, Ohtani N: Long-wavelength light emission from InAs quantum dots covered by GaAsSb grown on GaAs substrates.

    Physica E 2004, 21:295-299. Publisher Full Text OpenURL

  5. Ulloa JM, Drouzas IWD, Koenraad PM, Mowbray DJ, Steer MJ, Liu HY, Hopkinson M: Suppression of InAs/GaAs quantum dot decomposition by the incorporation of a GaAsSb capping layer.

    Appl Phys Lett 2007, 90:213105. Publisher Full Text OpenURL

  6. Liu HY, Steer MJ, Badcock TJ, Mowbray DJ, Skolnick MS, Suarez F, Ng JS, Hopkinson M, David JPR: Room-temperature 1.6 μm light emission from InAs/GaAs quantum dots with a thin GaAsSb cap layer.

    J Appl Phys 2006, 99:046104. Publisher Full Text OpenURL

  7. Ulloa JM, Reyes DF, Montes M, Yamamoto K, Sales DL, Gonzalez D, Guzman A, Hierro A: Independent tuning of electron and hole confinement in InAs/GaAs quantum dots through a thin GaAsSbN capping layer.

    Appl Phys Lett 2012, 100:013107. Publisher Full Text OpenURL

  8. Harmand JC, Caliman A, Rao EVK, Largeau L, Ramos J, Teissier R, Travers L, Ungaro G, Theys B, Dias IFL: GaNAsSb: how does it compare with other dilute III-V-nitride alloys?

    Semiconductor Sci Technol 2002, 17:778-784. Publisher Full Text OpenURL

  9. Molina SI, Sales DL, Galindo PL, Fuster D, Gonzalez Y, Alen B, Gonzalez L, Varela M, Pennycook SJ: Column-by-column compositional mapping by Z-contrast imaging.

    Ultramicroscopy 2009, 109:172-176. PubMed Abstract | Publisher Full Text OpenURL

  10. Ulloa JM, Celebi C, Koenraad PM, Simon A, Gapihan E, Letoublon A, Bertru N, Drouzas I, Mowbray DJ, Steer MJ, Hopkinson M: Atomic scale study of the impact of the strain and composition of the capping layer on the formation of InAs quantum dots.

    J Appl Phys 2007, 101:081707. Publisher Full Text OpenURL

  11. Mintairov AM, Sun K, Merz JL, Yuen H, Bank S, Wistey M, Harris JS, Peake G, Egorov A, Ustinov V, Kudrawiec R, Misiewicz J: Atomic arrangement and emission properties of GaAs(In, Sb)N quantum wells.

    Semiconductor Sci Technol 2009, 24:075013. Publisher Full Text OpenURL

  12. Molina SI, Guerrero MP, Galindo PL, Sales DL, Varela M, Pennycook SJ: Calculation of integrated intensities in aberration-corrected Z-contrast images.

    J Electron Microsc 2011, 60:29-33. Publisher Full Text OpenURL

  13. Hÿtch MJ, Snoeck E, Kilaas R: Quantitative measurement of displacement and strain fields from HREM micrographs.

    Ultramicroscopy 1998, 74:131-146. Publisher Full Text OpenURL

  14. Galindo PL, Kret S, Sanchez AM, Laval JY, Yanez A, Pizarro J, Guerrero E, Ben T, Molina SI: The Peak Pairs algorithm for strain mapping from HRTEM images.

    Ultramicroscopy 2007, 107:1186-1193. PubMed Abstract | Publisher Full Text OpenURL

  15. Wood DM, Zunger A: Epitaxial effects on coherent phase diagrams of alloys.

    Physical Review B 1989, 40:4062-4089. Publisher Full Text OpenURL

  16. Buyanova IA, Chen WM, Tu CW: Magneto-optical and light-emission properties of III-As-N semiconductors.

    Semiconductor Sci Technol 2002, 17:815-822. Publisher Full Text OpenURL

  17. Shin H, Kim JB, Yoo YH, Lee W, Yoon E, Yu YM: Enhanced strain of InAs quantum dots by an InGaAs ternary layer in a GaAs matrix.

    J Appl Phys 2006, 99:1-4. OpenURL

  18. Ciatto G, Harmand JC, Glas F, Largeau L, Le Du M, Boscherini F, Malvestuto M, Floreano L, Glatzel P, Mori RA: Anions relative location in the group-V sublattice of GaAsSbN/GaAs epilayers: XAFS measurements and simulations.

    Physical Review B 2007, 75:245212. OpenURL

  19. Hernández-Maldonado D, Herrera M, Alonso-González P, González Y, González L, Gazquez J, Varela M, Pennycook SJ, Guerrero-Lebrero MP, Pizarro J, Galindo PL, Molina SI: Compositional analysis with atomic column spatial resolution by 5th-order aberration-corrected scanning transmission electron microscopy.

    Microsc Microanal 2011, 17:578-581. PubMed Abstract | Publisher Full Text OpenURL

  20. Haxha V, Drouzas I, Ulloa JM, Bozkurt M, Koenraad PM, Mowbray DJ, Liu HY, Steer MJ, Hopkinson M, Migliorato MA: Role of segregation in InAs/GaAs quantum dot structures capped with a GaAsSb strain-reduction layer.

    Phys Rev B - Condens Matter and Mater Phys 2009, 80:165334. OpenURL

  21. Semenov A, Lyublinskaya OG, Solov'ev VA, Meltser BY, Ivanov SV: Surface segregation of Sb atoms during molecular-beam epitaxy of InSb quantum dots in an InAs(Sb) matrix.

    J Crystal Growth 2007, 301–302:58-61. OpenURL

  22. Miyoshi H, Suzuki R, Amano H, Horikoshi Y: Sb surface segregation effect on the phase separation of MBE grown InAsSb.

    J Crystal Growth 2002, 237–239(Part 2):1519-1524. OpenURL

  23. Sanchez AM, Beltran AM, Beanland R, Ben T, Gass MH, de la Pena F, Walls M, Taboada AG, Ripalda JM, Molina SI: Blocking of indium incorporation by antimony in III-V-Sb nanostructures.

    Nanotechnology 2010, 21:145606. PubMed Abstract | Publisher Full Text OpenURL

  24. Herrera M, Ramasse QM, Morgan DG, Gonzalez D, Pizarro J, Yanez A, Galindo P, Garcia R, Du MH, Zhang SB, Hopkinson M, Browning ND: Atomic scale high-angle annular dark field STEM analysis of the N configuration in dilute nitrides of GaAs.

    Physical Review B 2009, 80:125211. OpenURL

  25. Grillo V, Carlino E, Glas F: Influence of the static atomic displacement on atomic resolution Z-contrast imaging.

    Physical Review B 2008, 77:054103. OpenURL

  26. Ban K-Y, Bremner SP, Liu G, Dahal SN, Dippo PC, Norman AG, Honsberg CB: Use of a GaAsSb buffer layer for the formation of small, uniform, and dense InAs quantum dots.

    Appl Phys Lett 2010, 96:183101-183103. Publisher Full Text OpenURL

  27. Ulloa JM, Gargallo-Caballero R, Bozkurt M, Del Moral M, Guzmán A, Koenraad PM, Hierro A: GaAsSb-capped InAs quantum dots: from enlarged quantum dot height to alloy fluctuations.

    Phys Rev B - Condens Matter and Mater Phys 2010, 81:165305. OpenURL

  28. Klenovsky P, Krapek V, Munzar D, HumliCek J: Electronic structure of InAs quantum dots with GaAsSb strain reducing layer: localization of holes and its effect on the optical properties.

    Appl Phys Lett 2010, 97:203107. Publisher Full Text OpenURL