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Temperature-dependent Raman investigation of rolled up InGaAs/GaAs microtubes

Raul D Rodriguez1*, Evgeniya Sheremet1, Dominic J Thurmer23, Daniel Lehmann1, Ovidiu D Gordan1, Falko Seidel1, Alexander Milekhin4, Oliver G Schmidt23, Michael Hietschold5 and Dietrich RT Zahn1

Author affiliations

1 Semiconductor Physics, Chemnitz University of Technology, Chemnitz, D-09107, Germany

2 Material Systems for Nanoelectronics, Chemnitz University of Technology, Chemnitz, D-09107, Germany

3 Institute for Integrative Nanosciences, IFW Dresden, Helmholtzstrasse 20, Dresden, D-01069, Germany

4 Institute of Semiconductor Physics, Lavrentjev Av. 13, Novosibirsk, 630090, Russia

5 Solid Surfaces Analysis Group, Chemnitz University of Technology, Chemnitz, D-09107, Germany

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Citation and License

Nanoscale Research Letters 2012, 7:594  doi:10.1186/1556-276X-7-594

Published: 26 October 2012


Large arrays of multifunctional rolled-up semiconductors can be mass-produced with precisely controlled size and composition, making them of great technological interest for micro- and nano-scale device fabrication. The microtube behavior at different temperatures is a key factor towards further engineering their functionality, as well as for characterizing strain, defects, and temperature-dependent properties of the structures. For this purpose, we probe optical phonons of GaAs/InGaAs rolled-up microtubes using Raman spectroscopy on defect-rich (faulty) and defect-free microtubes. The microtubes are fabricated by selectively etching an AlAs sacrificial layer in order to release the strained InGaAs/GaAs bilayer, all grown by molecular beam epitaxy. Pristine microtubes show homogeneity of the GaAs and InGaAs peak positions and intensities along the tube, which indicates a defect-free rolling up process, while for a cone-like microtube, a downward shift of the GaAs LO phonon peak along the cone is observed. Formation of other type of defects, including partially unfolded microtubes, can also be related to a high Raman intensity of the TO phonon in GaAs. We argue that the appearance of the TO phonon mode is a consequence of further relaxation of the selection rules due to the defects on the tubes, which makes this phonon useful for failure detection/prediction in such rolled up systems. In order to systematically characterize the temperature stability of the rolled up microtubes, Raman spectra were acquired as a function of sample temperature up to 300°C. The reversibility of the changes in the Raman spectra of the tubes within this temperature range is demonstrated.

Rolled up tubes; Microtubes; Raman spectroscopy defects; Raman imaging; Strain imaging; Gallium arsenide; Dependent Raman spectroscopy; Gallium arsenide TO phonon