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Porous silicon nanocrystals in a silica aerogel matrix

Jamaree Amonkosolpan1, Daniel Wolverson1*, Bernhard Goller12, Sergej Polisski13, Dmitry Kovalev1, Matthew Rollings1, Michael D W Grogan14 and Timothy A Birks1

Author Affiliations

1 Department of Physics, University of Bath, Claverton Down, Bath, BA2 7AY, UK

2 Infineon Technologies AG, Siemensstrasse 2, Villach, 9500, Austria

3 Department of Energy & Hydrocarbon Chemistry, Graduate School of Engineering, Kyoto University, Nishikyo-ku, Kyoto, 615-8510, Japan

4 Department of Electrical and Computer Engineering, Boston University, Boston, MA, 02215, USA

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Nanoscale Research Letters 2012, 7:397  doi:10.1186/1556-276X-7-397

Published: 17 July 2012


Silicon nanoparticles of three types (oxide-terminated silicon nanospheres, micron-sized hydrogen-terminated porous silicon grains and micron-size oxide-terminated porous silicon grains) were incorporated into silica aerogels at the gel preparation stage. Samples with a wide range of concentrations were prepared, resulting in aerogels that were translucent (but weakly coloured) through to completely opaque for visible light over sample thicknesses of several millimetres. The photoluminescence of these composite materials and of silica aerogel without silicon inclusions was studied in vacuum and in the presence of molecular oxygen in order to determine whether there is any evidence for non-radiative energy transfer from the silicon triplet exciton state to molecular oxygen adsorbed at the silicon surface. No sensitivity to oxygen was observed from the nanoparticles which had partially H-terminated surfaces before incorporation, and so we conclude that the silicon surface has become substantially oxidised. Finally, the FTIR and Raman scattering spectra of the composites were studied in order to establish the presence of crystalline silicon; by taking the ratio of intensities of the silicon and aerogel Raman bands, we were able to obtain a quantitative measure of the silicon nanoparticle concentration independent of the degree of optical attenuation.

porous silicon; nanoparticle; luminescence; Raman; silica aerogel; oxygen; energy transfer; 78.66.Jg; 78.67.-n; 78.67.Bf