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Open Access Nano Express

Selective preparation of zero- and one-dimensional gold nanostructures in a TiO2 nanocrystal-containing photoactive mesoporous template

Go Kawamura1*, Teruhisa Okuno2, Hiroyuki Muto12 and Atsunori Matsuda12

Author affiliations

1 Department of Electrical and Electronic Information Engineering, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi, 441-8580, Japan

2 Department of Environmental and Life Sciences, Toyohashi University of Technology, 1-1 Hibarigaoka, Tempaku-cho, Toyohashi, Aichi, 441-8580, Japan

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Citation and License

Nanoscale Research Letters 2012, 7:27  doi:10.1186/1556-276X-7-27

Published: 5 January 2012

Abstract

Nanocrystallized SiO2-TiO2 with tubular mesopores was prepared via the sol-gel technique. Gold was deposited in the tubular mesopores of the nanocrystallized SiO2-TiO2. The shape of the gold was varied from one-dimensional [1-D] to zero-dimensional [0-D] nanostructures by an increase in TiO2 content and ultraviolet [UV] irradiation during gold deposition. 1-D gold nanostructures [GNSs] were mainly obtained in the mesopores when a small amount of TiO2-containing mesoporous SiO2-TiO2 was used as a template, whereas the use of a template containing a large amount of TiO2 led to the formation of shorter 1-D or 0-D GNSs. UV irradiation also resulted in the formation of 0-D GNSs.

PACS: 06.60.Jn (sample preparation); 81.07.Gf (nanowires); 81.16.Be (chemical synthesis methods).

Keywords:
mesoporous; titania; template; gold; nanostructures; shape control; photocatalysis; surface plasmon resonance