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Hybrid polymer/ZnO solar cells sensitized by PbS quantum dots

Lidan Wang12, Dongxu Zhao1*, Zisheng Su1 and Dezhen Shen1

Author affiliations

1 State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, Changchun 130033, People's Republic of China

2 Graduate School of Chinese Academy of Sciences, Beijing 100039, People's Republic of China

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Citation and License

Nanoscale Research Letters 2012, 7:106  doi:10.1186/1556-276X-7-106

Published: 7 February 2012

Abstract

Poly[2-methoxy-5-(2-ethylhexyloxy-p-phenylenevinylene)]/ZnO nanorod hybrid solar cells consisting of PbS quantum dots [QDs] prepared by a chemical bath deposition method were fabricated. An optimum coating of the QDs on the ZnO nanorods could strongly improve the performance of the solar cells. A maximum power conversion efficiency of 0.42% was achieved for the PbS QDs' sensitive solar cell coated by 4 cycles, which was increased almost five times compared with the solar cell without using PbS QDs. The improved efficiency is attributed to the cascade structure formed by the PbS QD coating, which results in enhanced open-circuit voltage and exciton dissociation efficiency.