This article is part of the series Micro&Nano2010: Special Symposium on Nanomaterials for sensing and energy harvesting devices.

Open Access Nano Express

Efficient thermoelectric energy conversion on quasi-localized electron states in diameter modulated nanowires

Xanthippi Zianni

Author affiliations

Department of Applied Sciences, Technological Institution of Chalkida, Psachna, 34400 Evia, Greece

Citation and License

Nanoscale Research Letters 2011, 6:286  doi:10.1186/1556-276X-6-286

The electronic version of this article is the complete one and can be found online at:

Received:9 December 2010
Accepted:4 April 2011
Published:4 April 2011

© 2011 Zianni; licensee Springer.

This is an Open Access article distributed under the terms of the Creative Commons Attribution License (, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.


It is known that the thermoelectric efficiency of nanowires increases when their diameter decreases. Recently, we proposed that increase of the thermoelectric efficiency could be achieved by modulating the diameter of the nanowires. We showed that the electron thermoelectric properties depend strongly on the geometry of the diameter modulation. Moreover, it has been shown by another group that the phonon conductivity decreases in nanowires when they are modulated by dots. Here, the thermoelectric efficiency of diameter modulated nanowires is estimated, in the ballistic regime, by taking into account the electron and phonon transmission properties. It is demonstrated that quasi-localized states can be formed that are prosperous for efficient thermoelectric energy conversion.


A measure of the thermoelectric efficiency of a material is the dimensionless figure of merit ZT S2σT/κ, where σ is the conductivity, S is the thermopower, κ is the thermal conductivity and T is the absolute temperature. In nanostructures, quantum confinement of electrons and phonons favours their thermoelectric transport properties, resulting in increased thermoelectric efficiency [1]. Nanowires and arrays of nanodots are currently attracting much research interest. It has been theoretically shown that nanodots can have very high thermoelectric efficiencies due to their discrete energy spectrum [2-4]. Quantum confinement causes enhancement of ZT in nanowires. Considerably high values of the figure of merit have been found in very thin wires [5-8]. Despite the noticeable progress in the fabrication of wires with high aspect ratios, the poor mechanical properties of very thin wires is a drawback for developing devices based on them.

Recently, we proposed that increase of the thermoelectric efficiency could be achieved by modulating the diameter of the nanowires [9]. We showed that the electron thermoelectric properties depend strongly on the geometry of the diameter modulation. In this Letter, we focus on the electron propagation states that we reported to have high values of thermoelectric figure of merit when phonon conduction was neglected. The thermoelectric efficiency of these states is estimated, here, by taking into account the electron and phonon transmission properties. In what follows, it is shown that efficient thermoelectric energy conversion can be achieved on electron quasi-localized states in diameter modulated nanowires.

Theoretical model

The relation between the thermoelectric transport coefficients and the transmission coefficient T(E) is given by Landauer-Büttiker formalism:





where G is the conductance, S is the thermopower, K is the thermal coefficient and κe is the electron thermal conductance. The symbol f denotes the Fermi distribution function and EF is the Fermi energy. The thermoelectric efficiency is measured by the dimensionless figure of merit:


where κph is the phonon thermal conductance. An optimal thermoelectric efficiency ZT0 can be estimated considering only the electronic contribution in the thermal conductance, whereby




The coefficient α is a measure of the effect of phonon conduction on the thermoelectric efficiency. When phonon conduction is non-negligible, the coefficient α is smaller than 1 and ZT is smaller than ZT0.

Results and discussion

The formalism of the previous section explicitly shows that the transport properties of an electron propagating through a wire are sensitive to the energy dependence of the transmission coefficient. Energy selectivity is provided for electrons by their Fermi distribution at the electrodes. The electron Fermi energy, EF, varies depending on the electrode material and/or doping. It can also be varied electrostatically by an external gate in a gated-wire configuration. The transmission coefficient of an electron travelling ballistically through a uniform straight wire is a step-like function of its Fermi energy, EF [10]. If we now consider a wire with diameter modulation by units that assume discrete energy spectra, e.g. quantum dots (Figure 1), the transmission coefficient will have transmission resonances, transmission bands and transmission gaps. The shape of T(E) is sensitive to the geometry of the modulation and to the relative dimensions of the modulating parts of the wire. In Figure 2a, the transmission coefficient is shown for wire diameter modulation by one dot attached with two narrow constrictions. For the dimensions chosen here for illustration (Figure 1), the narrow constrictions have a propagation threshold of approximately 56 meV. Transmission resonances (R in Figure 2) occur in T(E) at electron energies at which no-propagating waves can exist in the narrow constrictions and which correspond to quasi-bound states of the dots. In this case, electronic transport is based on evanescent-mode coupling as in tunnelling phenomena in heterojunctions. Coupling between propagation resonances with small energy separation, result in the formation of narrow propagation bands (NB in Figure 2) in the transmission gap of the constrictions. Electron propagation states within the transmission gap of the constrictions can be interpreted as quasi-localized states.

thumbnailFigure 1. Sketch diagram of the diameter modulated nanowire. Two-dimensional GaAs wires have been used for illustration. The dimensions of the diameter modulations are: (a) the thick parts are 100 nm long and 50 nm thick, (b) the thin constrictions are 5 nm long and 10 nm thick, and (c) the dots are 20 nm long and 35 nm thick.

thumbnailFigure 2. The energy dependence of the transmission coefficient. T(E) is shown for: (a) a uniform straight wire 10 nm thick (black) and of a wire modulated by one dot (red), (b) a wire modulated by one dot (red) and by three dots (blue).

At the transmission resonance R, ZT0 has been found to increase with increasing temperature T and decreasing broadening Γ (Figure 3). This behaviour can be qualitatively interpreted by the following expression that has been derived for an isolated resonance assuming a symmetric Lorentzian-function for the transmission coefficient [11]:

thumbnailFigure 3. The electron figure of merit ZT0 versus EF at T = 5 K (red), 10 K (blue) and 50 K (green).


where Εres and Γ are the energy and the broadening of the resonance respectively.

At R, ZT0 (Figure 3) has very high values for small energy broadening Γ [9]. It should be noticed though, that the corresponding power factor is small (Figure 4). This can be interpreted by the following formula [11]:

thumbnailFigure 4. The power factor S2GT versus EF at T = 5 K (red), 10 K (blue) and 50 K (green).


The transmission coefficient deviates from the symmetric-Lorentzian function because the transmission resonance R is not perfectly isolated. Due to coupling between R and the neighbouring transmission states, T(E) is asymmetric. At low temperatures, the asymmetry of T(E) has small effect on the conductance G and the thermopower S. G has a symmetric peak form, S is antisymmetric around the peak of G and S2GT has a double-peak form [2,4]. The asymmetry of T(E) has a more significant effect on the electron thermal conductance κe that is also asymmetric with a peak shifted towards higher energies with respect to the zero of S2GT (Figure 5). κe is sensitive to the shape of T(E) across the propagation resonance because the off-resonance states mainly contribute to it. The electron thermal conductance κe would be zero for a single energy level with zero broadening (Γ = 0), as it has been shown for a single delta-like level of a quantum dot [2]. Due to the asymmetric κe, ZT0 is also asymmetric (Figure 3). At elevated temperatures, Equation 9 is not a good approximation for ZT0, because then the electron distribution is thermally broadened and effects of coupling to neighbouring states become important.

thumbnailFigure 5. The electron thermal conductance κe versus EF at T = 5 K (red), 10 K (blue) and 50 K (green).

At the narrow band below the transmission band threshold of the constriction, NB (Figure 2), ZT0 has considerably smaller values than at R due to higher electron thermal conductance at NB than at R (Figure 5). The power factor, S2GT, is considerably higher at NB than at R (Figure 4). At NB, a significant increase of ZT0 is found with increasing temperature due to: (i) increase of S2GT and (ii) decrease of κe due to heat leakage through propagation band states at higher energies.

At NB, ZT0 increases when more modulating units are added (Figure 6) because a narrow band with sharper transmission thresholds is formed. This can be seen by comparing T(E) for a single dot and for a finite superlattice of three dots (Figure 2b). It should be noted that the formation of the transmission band edges is completed after a small number of periods and adding more dots does not result in any further increase in ZT0. It should, though, be emphasized that adding more modulating units could result in increase in ZT (Equation 7) due to decreased κph. Phonon conductance decreases due to additional phonon scattering when additional inhomogeneities are introduced in a nanowire.

thumbnailFigure 6. ZT0 versus EF, at T = 10 K, for nanowires modulated by one dot (red), three dots (blue) and five dots (dark green).

It is well known that phonon conduction decreases in nanostructures due to phonon scattering on boundaries and interfaces. In heterostructures, optical and acoustic phonons have been shown to occupy quasi-bound states within narrow bands separated by gaps [12,13]. It has been shown [14,15] that in an ideal quantum wire the total acoustic phonon transmission probability exhibits perfect transmission steps. A perfect quantum thermal plateau exists, and at T = 0, its value approaches a universal value, . Quantum wires attached with inhomogeneities such as abrupt junctions and stub structures have already been reported [16-19]. In wires modulated by dots, the phonon transmission spectra have shown to display complex peak-dip structures. The thermal conductance plateau is destroyed and the thermal conductance decreases due to phonon scattering. It has been found [17-19] that the phonon thermal conductance can be adjusted by the attached scattering and it can become smaller than κ0. We have found that the electron thermal conductance can also be smaller than κ0. The ratio of the two contributions to the thermal conductance, κph/κe, determines the value of coefficient α, i.e. the decrease of ZT relative to ZT0.

The low temperature phonon conductance of a wire modulated by dots has been estimated in Refs. [17-19]. We have taken into account the conclusions to estimate ZT.

At R, ZT is found much smaller than ZT0 (compare Figures 3 and 7). This is explained by that: (i) the power factor S2GT is small (Figure 4), and (ii) the reduction of κph is expected to be smaller than the reduction of κe. In diameter modulated wires, wave interference effects result in reduction of the thermal conductance for both electrons and phonons. The significant reduction of κe is due to the formation of transmission resonances for electrons and the energy selectivity provided by the Fermi distribution. Such transmission resonances have not been found for phonons [17-19]. More than one phonon modes contribute to the phonon conduction. Each mode has its own T(E) and energy selectivity is not provided by the phonon distribution. It is, therefore, unlike that, in diameter modulated nanowires, κph could be reduced as much as κe at R. This remains, however, to be further explored.

thumbnailFigure 7. The total figure of merit ZT versus EF. The curves are for : a uniform nanowire 10 nm thick (black) with κph = 1.5 κ0, and nanowires modulated by one dot (red) with κ ph = 0.5 κ0 and by five dots (dark green) with κ ph = 0.1 κ0, at T = 10 K.

At NB, ZT decreases relative to ZT0 but it has values close to and above 1 (Figure 7). This is because: (i) the power factor S2GT is not very small (Figure 4) in this case, and (ii) the ratio of κph/κe can be of the order of 1. In the data shown in Figure 7, it has been considered that κph is always reduced due to the diameter modulation [17-19]. Hence, ZT of the modulated wire is found higher than that of a uniform thin wire with diameter equal to that of the thin constrictions (Figure 1). It is thereby indicated that increase of the thermoelectric efficiency of nanowires could be achieved by modulating their diameter instead of making them very thin and mechanically unstable.

In the ballistic regime, the thermoelectric efficiency of diameter modulated nanowires is directly related to the energy dependence of the transmission coefficient. For both electrons and phonons, T(E) is sensitive to the geometry of the modulated nanowires [9,17-19]. Geometry optimization of the diameter modulation could result in optimal electron thermoelectric properties and minimum phonon conduction. This task is very challenging because several geometry lengths are involved. For instance, the formation of quasi-localized states depends on the width and the length of the constrictions relative to the dimensions of the modulating units, by the number of modulating units, by disorder in arrays of non-identical modulation units. The recent progress in the fabrication of nanowires using well-controlled techniques (both epitaxial and etching) could allow for geometry optimization and development of efficient thermoelectric applications based on modulated nanowires.


The thermoelectric efficiency of diameter modulated nanowires has been estimated by taking into account the electron and phonon transmission properties. It has been demonstrated that quasi-localized electron states can be formed that are prosperous for efficient thermoelectric energy conversion. Diameter modulated nanowires provide an architecture suitable for optimization of the transport properties of both electrons and phonons.

Competing interests

The author declares that they have no competing interests.


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