One-Step UV-Induced Synthesis of Polypyrrole/Ag Nanocomposites at the Water/Ionic Liquid Interface
1 Key Laboratory for Green Chemical Process of Ministry of Education, School of Materials Science and Engineering, Wuhan Institute of Technology, State Key Laboratory of Coordination Chemistry, Nanjing University, 430073, Wuhan, People’s Republic of China
2 College of Chemistry, Chemical Engineering and Materials Sciences, Soochow University, 215123, Suzhou, People’s Republic of China
Nanoscale Research Letters 2009, 5:433-437 doi:10.1007/s11671-009-9501-9Published: 28 November 2009
Polpyrrole (PPy)/Ag nanocomposites were successfully synthesized at the interface of water and ionic liquid by one-step UV-induced polymerization. Highly dispersed PPy/Ag nanoparticles were obtained by controlling the experimental conditions. The results of Fourier-transform infrared spectroscopy, X-ray diffraction, transmission electron microscopy and X-ray photoelectron spectroscopy revealed that the UV-induced interface polymerization leaded to the formation of PPy incorporating silver nanoparticles. It was also found that the electrical conductivity of PPy/Ag nanocomposite was about 100 times higher than that of pure PPy.