Laser photolysis of WCl6 in ethanol and a specific mixture of V2O5 and VCl3 in ethanol lead to carbon modified vanadium and tungsten oxides with interesting properties. The presence of graphene’s aromatic rings (from the vibrational frequency of 1,600 cm−1) together with C–C bonding of carbon (from the Raman shift of 1,124 cm−1) present unique optical, vibrational, electronic and structural properties of the intended tungsten trioxide and vanadium dioxide materials. The morphology of these samples shows nano-platelets in WOx samples and, in VOx samples, encapsulated spherical quantum dots in conjunction with fullerenes of VOx. Conductivity studies revealed that the VO2/V2O5 nanostructures are more sensitive to Cl than to the presence of ethanol, whereas the C:WO3 nano-platelets are more sensitive to ethanol than atomic C.
Keywords:Carbon; VO2; V2O5; WO3; Laser; Photolysis; Sensors
The study of vanadium and tungsten oxides has been undertaken extensively in recent years due to their respective thermo-chromic and electro-chromic and hence gas-chromatic properties. Since the discovery of the metal-to-insulator transition (MIT) at 340 K of VO2 in 1959 by Morin  and electro-chromism of WO3 in 1975 by Faughnan [2,3], and also due to the fact that the tungsten metal is, so far, the best known dopant in VO2 to reduce the MIT temperature to room temperature, the study of the two materials together is expected to yield a good understanding of their MIT behaviours especially at the nano-scale as discussed by this group and others previously [4-6]. To date, self assembly of these materials has been achieved by a number of techniques, including: hydrothermal techniques , employing templates either with polymers or pre-assembled carbon nanotubes , CVD epitaxial growth , sol–gel , ion implantation , hot-wire CVD , sputtering  and ultrasonic spray pyrolysis [14-18]. Also V2O5 capsules , WO3 nano-rods and nano-wires and nano-arrays [20-22] have previously been obtained using several techniques. Laser synthesis methods have been of particular interest and have been followed by this group previously [23,24]. The coherent, intense and almost monochromatic laser light allows it to be tuned to selectively dissociate specific bonds in a precursor molecule either by resonance between the laser frequency and the bond’s natural frequency or via multi-photon absorption. This leads to products that can be unique and different from those obtained by traditional thermal deposition techniques. In this work, we followed a process called laser solution photolysis (LSP) that has been used previously to obtain FePt ultra-fine powders . Organo-metallic precursors containing Fe and Pt, respectively were employed in the presence of a polymer. The polymer was employed to reduce agglomeration of the nano-particles produced. Further examples of the technique include, gold nano-particles produced by UV light irradiation of gold chloride [26-28], iron-based nanoparticles produced by utilising UV light absorbing ferrocene and iron(II) acetylacetonate [29,30] and laser ablation in a solid–liquid interface [31,32]. In this study, we used, as precursors, metal ethoxides which were produced from metal chlorides.
During the preparation of the tungsten-based precursor solution, a complicated set of reactions take place over several days. This is indicated by the many continuous changes in the colour of the mixture of WCl6 and ethanol. In accordance with the formation of vanadium ethoxide reported previously by Livage et al. , the possible reaction path for the dissolution of WCl6 in ethanol is:
Most of the HCl is lost as gas bubbles, which visibly effervesce from the liquid. Similar reaction routes are expected for the vanadium dioxide precursor solution.
For the synthesis of WO3, an aliquot of 5.3 mg of a dark-blue WCl6 powder was dissolved in 500 ml of ethanol in an argon environment, resulting in a light blue to light-yellow liquid. When this liquid was irradiated with 5,000 saw-tooth-shaped pulses from a 248-nm KrF excimer laser, with a fixed energy of 10 mJ at 8 Hz, the light yellow liquid turned to blue-black. For the production of VO2, one part of V2O5(in which molecule the V takes the valence of 5+) and two parts of VCl3 (where V has a valence of 3+) were dissolved in ethanol. The ratio was chosen to produce a stoichiometry of VO2 in which molecule the V atom has a valence of 4+.
Scanning electron microscopy was carried on a Gemini Neon 40 FEG SEM equipped with a focussed ion beam (FIB) gun. A drop of the as-irradiated liquid was dropped onto a glass slide and Si(111) surface. Raman spectroscopy was carried out using a Jobin–Yvon T64000 Raman spectrograph with a 514.5-nm line from an argon ion laser. The power of the laser at the post-annealed samples (0.384 mW) was small enough in order to minimise localised heating of the sample. The T64000 was operated in single spectrograph mode, with the 1,800 lines/mm grating and a 50× objective on the microscope. A drop of such liquid was also placed on carbon holey film supported by copper grids for high resolution transmission electron microscopy on a JEOL 2100 equipped with a LaB6 filament and a Gartan U1000 camera with 2,028 × 2,048 pixels.
Results and Discussion
When the tungsten ethoxide is irradiated with a 10.6-μm CO2 laser beam, the O–C bond, whose vibrational frequency of 1,000 cm−1 is close to that of the laser (944 cm−1), is selectively dissociated by multi-photon absorption to produce WO3 via:
The laser dissociation route in Eq. 2 was reported previously when non-stoichiometric WO3 thin films  were observed in laser pyrolysed samples by Raman spectroscopy. The films became stoichiometric WO3 nano-wires after further post-deposition annealing in a furnace . In the same sample, isolated carbon material such as multi-wall carbon nano-tubes were seen under TEM. It is presumed that the H2 evaporated during the laser pyrolysis and annealing. Furthermore, as shown in Eq. 2, carbon is segregated and deposits as one or more of its allotropes such as tetrahedrally amorphous carbon, graphite and diamond. However, carbon can also be found in the matrix of WO3 as a dopant as in Eq. 3. This has been observed in the current set of experiments.
When the same precursors are irradiated with the 248-nm beam from the KrF excimer laser, the W(OR)6 liquid turns blue-black before stabilising to a yellow colour after a few days, whereas no colour change is seen in the vanadium precursor. It is suggested that at this wavelength, a different bond is dissociated namely the C–H bond which has a frequency of between 3,000 and 3,300 cm−1 compared to the laser frequency of 40,322 cm−1(at λ = 248 nm). The C–H bond then has a higher probability of being dissociated than the O–C bond, since the C–H bond is only 10 times lower than the laser frequency when compared to the O–C which is 40 times lower. Also, the C–H bond is capable of oscillating closer to the laser frequency via other higher order vibrational modes.
The scanning electron microscopy image of carbon modified WOx nano-platelets presented in Fig. 1 shows significant stacking between the platelets and the formation of chains. A relatively narrow size distribution of the particles can be observed. Local EDS (inset of Fig. 1) demonstrates the purity of the carbon modified WO3 sample. A carbon shoulder peak at X-ray energy of about 0.3 keV could clearly be observed.
Figure 1. Scanning electron micrograph of the carbon modified WO3 particles produced by laser solution photolysis. The inset shows elemental composition of the sample by EDS
X-ray diffraction (XRD) results from the carbon modified WO3 nano-platelets are presented in Fig. 2. In our carbon modified WO3 sample, the usual triplet peaks at 2θ values of 23.117o, 23.583o and 24.583o corresponding to the Miller indices of (002), (020) and (200) (International Crystallographic Diffraction Data (ICDD) Powder Diffraction File (PDF) 83-0950) are found to be shifted to 2θ = 23.736o, 25.463o and 27.325o, respectively. This indicates that this is indeed the WO3 crystal but its structure is significantly distorted by dopants. Based on the initial reagents and EDS spectrum in the inset of Fig. 1, the dopant for WO3 nanoplates is only carbon. No hydrogen or chlorine peaks were found. From more searches in the ICDD database, the PDF No 40-0752 of C6WO6 has a strong peak at 2θ = 15.595o with the (hkl) coordinates of (002) or (101) which closely matches the shoulder peak in the present sample at 2θ = (14.63 ± 0.54)o. This peak is not found in all files of stoichiometric WO3. This suggests that carbon is the most important dopant in this case.
Figure 2. X-ray diffraction of the carbon modified WO3 nano-platelets. Note the shoulder peak at 2θ = 14.63o which closely matches that of C6WO6 at 2θ = 15.595o
The distortion of the WO3 structure observed by high resolution transmission electron microscopy (Fig. 3) supports the XRD results. The (002), (020) and (200) planes in stoichiometric WO3(PDF 80-0950) are expected to have d - spacings of 3.8443, 3.7694 and 3.6499 Å. Based on the TEM observations of our carbon modified WO3 crystals, the inter-planar d - spacings are 4.70, 3.52 and 3.38 Å, respectively.
Figure 3. a Low magnification TEM image of the WOx showing stacking of nano-platelets, b cross-sectional view of one stacking, showing each platelet can be up to 20 nm thick with one preferred direction of stacking as shown by the inset of the image’s FFT. c Top-view of two platelets stacked together showing the inter-planar spacing, angles and the two-dimensional growth shown by FFT of the image in the inset of c
Our VOx sample was also prepared similarly and observed by TEM. Triangular envelope-like structures of about 400 nm on each side of the triangle are the predominant polymorphs. The triangles are thin layers of VOx with an interplanar spacing of 3.75 Å as shown in Fig. 4. Observed at higher magnification, the layers were found to be envelopes containing spherical nano-particles with an average size of 6 nm. These VOx quantum dots which can be solid (multi-walled) spheres or VOx fullerenes are found to have the same size distribution, as shown in the inset (d) of Fig. 4. An EDS spectrum of such nanostructures placed on Si(111) surface (inset (e) in Fig. 4) showed peaks for V and O alongside the major Si(111) from the substrate and trace amounts of Na, Cl and Ca. This confirms the morphology studies done by SEM of such a sample (not shown here) where the triangular capsules were interspaced by large cubic crystals presumably of NaCl and CaCl2 which have been segregated from the V2O5/VO2 triangular capsules. Also, carbon doping is confirmed in the capsules by the C shoulder peak at 0.3 keV.
Figure 4. a Low magnification TEM of the triangular envelopes of VOx, b one pocket at higher magnification, showing the small voids and solid spheres, c HRTEM of one of the hollow quantum dots and, d size distribution histograms for the hollow and solid quantum dots of VOx and e EDS of the C: V2O5/VO2 nanostructures showing their elemental composition
From Raman spectroscopy of the carbon modified WOx shown in Fig. 5, a slight red-shift from 705 to 674 cm−1 can be observed, corresponding to the bending modes in WO3 of O–W–O. The suppression of the stretching mode of the same bond at 800 cm−1 is presumed to be due to the presence of the dopants. Only the surface W=O stretching mode at 958 cm−1 is unchanged by the new structure. This peak is broadened towards the higher wave-numbers—beyond 1,000 cm−1. It should also be noted that the O–C bond found in ethanol, which could be the bridge between the dopant carbon and the WO6 octahedra in the WO3 structure in this case, has a vibrational frequency of 1,000 cm−1. The presence of carbon is signified by the peak close to 1,580 cm−1 showing aromatic rings of carbon which form the perfect graphite sp2 bonding structure. We did not find any D band at 1,354 cm−1 in this sample showing that there is no disorder in the aromatic network structure of the dopant C. However, there is a new sharp peak at 1,124 cm−1 which could be assigned to C–C bond vibration, in agreement with previously observed glucose carbon vibrations at 1,126 cm−1. Ferrari et al.  previously observed a peak at 1,060 cm−1 in diamond-like-carbon and assigned this phonon frequency to sp3 bonding but this was found to be too far from the 1,124 cm−1 peak observed presently to be acceptable.
Figure 5. Raman spectra of the carbon modified WOx nano-platelets showing the characteristics peaks for the crystal WO3 and those of aromatic carbon at 1,600 cm−1. The peak at 1,124 cm−1 closely matches that of 1,126 cm−1 assigned to C–C bond vibration
Fourier-transform infrared spectroscopy of the carbon modified WO3(Fig. 6) supports the results obtained by Raman spectroscopy. The strong and broad absorption peak at 598 cm−1 with its shoulder at 730 cm−1 can be assigned to the O–W–O stretching vibrations in the WO3 structure, whereas the 916 cm−1 peak corresponds to the W=O surface stretching modes due to dangling oxygen bonds. The red-shift from the Raman allowed 960 cm−1 to the IR allowed 916 cm−1 could be due to the loading of carbon on these bonds. Carbon doping is confirmed by the presence of the peaks assigned to the C–O bonding at 1,000 and 1,054 cm−1; these could not be observed in Raman spectroscopy for reasons not established yet. The 1,600 cm−1 phonon frequency assigned to the perfect graphite’s aromatic carbon ring is confirmed by FTIR as previously seen in Raman spectroscopy. The group of absorption peaks from 3,000 to 3,550 cm−1 have previously been assigned to OH bonds which suggest that some terminal oxygen atoms in the WO3 structure are not only bonded to the carbon aromatic rings but also to hydrogen. No C–H bonds were found by FTIR.
Figure 6. Infrared spectra of two samples of carbon-doped WO3. Sample 2 was exposed to carbon for a longer period of time than sample 1. The carbon doping is confirmed by the existence of the carbon–oxygen bond at 1,000 and 1,054 cm−1 in both samples
Possible Mechanism of Formation of the Triangular Envelopes and VOx Inorganic Fullerenes
Since the discovery of carbon nano-tube structure in the early 1980s, Tenne and co-workers also reported similar structures in WSe2 and MoS2. The argument was that metal chalcogenides and oxides are also capable of arranging their unit cells in a hexagonal close packing as in carbon, thereby forming a layer of atoms whose edges leave dangling bonds. These bonds cause intense attractive forces which compel the layer to fold on itself into various shapes such as tubes, scrolls and rods. Formation of fullerenes is due to defects which are found to be pentagonal, rectangular and triangular bonds, which are possible in all transition metal compounds. Different processes of formation of, for instance, V2O5 capsules [37,38] have led authors to suggest various mechanisms. We suggest that the formation of our triangular envelopes/capsules starts with the formation of closely packed hexagonal 2-D layers when the VOx is subjected to the laser beam. This assumption is based on the known experimental and theoretical facts from computer modelling that V2O5 is capable of wrapping into V2O5 nano-tubes  either as a zig–zag framework or in an arm chair structure . It is also known that a mixture of V4+ and V5+ in (VIVO)[VVO4].0.5[C3N2H12] can lead to a layered structure . The organic layer intercalates the inorganic counterpart with the latter containing square pyramids formed by V4+ ions and tetrahedral pyramids formed by V5+ ions. On this layer are randomly scattered fullerenes of the same material which have self-assembled under the same laser beam. These fullerenes together with dangling bonds on the layer periphery exert intense attractive forces which cause the layer to fold on itself in a certain pattern. A schematic cartoon of the possible formation of the VO2/V2O5 triangular envelops that encapsulate the VO2/V2O5 QDs and the VO2/V2O5 fullerenes are shown in Fig. 7. A hexagonal packing in a zig–zag fashion ends up having arm-chair structure dangling bonds in the periphery of the hexagon. The dangling bonds and the van der Waal’s forces from the particles sitting on the surface compel this sheeting to wrap on itself from a hexagon, through intermediate stages, into a triangular envelope. The foldings are along arm-chair structure on two sides of the triangle AEC (sides AC and EC in Fig. 7 (a)) and along a zig–zag structure on the third side of the triangle (side AE).
Figure 7. A schematic representation of how the triangular envelops of VOx sheets form a a hexagonally packed layer of V2O5/VO2 with some QDs of same material scattered randomly on it b the layer folds along zigzag AE, armchair EC and armchair AC of triangle AEC c the folding of triangular flaps ABC, CDE and EDF progresses until d the triangular envelop AEC is formed. The enveloped spherical particles are either e multi-walled V2O5/VO2 fullerenes or f single walled V2O5/VO2 fullerenes
Raman spectroscopy of these structures (shown in Fig. 8) supports the fact that there exists mixed valence of V4+(signified by the 300 cm−1 phonon which is an undertone of the main 600 cm−1 peak which in these samples is masked by the strong Si–Si background noise from the substrate at 520 cm−1) and V5+ from 930–970 cm−1. The peak at 1,120 cm−1 suggests the presence of C–C bonds in the VO2/V2O5 structure. As opposed to the carbon modified WO3 nano-platelets which showed aromatic carbon apart from C–C bonds, Raman spectroscopy showed no aromatic rings in VO2/V2O5 triangular envelopes.
Figure 8. Raman spectrum of the VO2/V2O5 triangular capsules containing VO2/V2O5 fullerenes and quantum dots showing a strong peak at 1,120 cm−1 which suggests C–C intercalation of the VO2/V2O5 structure
Influence of Chlorine on the Conductance of VOx Structures
Two samples of the VO2/V2O5 triangular envelopes were produced from laser photolysis of VCl3 in ethanol and V2O5 added to VCl3 in ethanol were subjected to conductivity tests using a four-point probe technique by employing a Keithley Semiconductor Characterisation System (Fig. 9). Pure V2O5 powder shows negligible conductance (inset of Fig. 9) which is enhanced by performing laser photolysis in the presence of VCl3 in ethanol. The conductance is highest in the photolysed VO2/V2O5 nanostructures produced from the precursor of VCl3 in ethanol. This suggests that in the first photolysis, we form VOx nanostructures of lower content of Cl than in the second one. Furthermore, the VOx structures are sensitive to the presence of Cl which could indicate that VOx nanostructures are potential chlorine sensors. In both samples, the presence of chlorine shows a more pronounced change than the presence of ethanol.
Figure 9. The high conductance in photolysed VCl3 in ethanol shows the higher sensitivity of VO2/V2O5 triangular envelopes to chlorine exposure compared to ethanol. Inset: the i-v curve for pure V2O5 powder
Effect of Ethanol on the Conductance of WOx Platelets
Two C:WO3 samples produced by laser solution photolysis were dried for two and 3 weeks respectively. The sample dried for 3 weeks was assumed to be more heavily carbon-doped and it only showed slightly more conductivity than the sample dried for 2 weeks as shown in the inset of Fig. 10. However, exposure of these C:WO3 nano-platelets to ethanol significantly increased the conductance, confirming that WO3 can act as a sensor of ethanol.
Figure 10. The presence of ethanol in the C:WO3 nano-platelets shows a more pronounced change in conductivity than the presence of carbon
Production of nano-platelets of carbon modified WO3 and 6-nm encapsulated VOx quantum dots by laser solution photolysis have been achieved. Conductivity studies revealed that the VO2/V2O5 nanostructures are more sensitive to atomic C than to the presence of ethanol, whereas the C:WO3 nano-platelets are more sensitive to ethanol than atomic C.
We acknowledge Nosipho Moloto for her assistance with FIB FEGSEM, Brian Yalisi for the KrF laser and Lerato Shikwambana and Malcolm Govender for the starting materials. Financial and infrastructural support from the CSIR National Laser Centre and characterisation facilitation of the CSIR National Centre for Nano-Structured Materials are acknowledged.
This article is distributed under the terms of the Creative Commons Attribution Noncommercial License which permits any noncommercial use, distribution, and reproduction in any medium, provided the original author(s) and source are credited.
Phys. Rev. Lett.. 1959, 3:34.
COI number [1:CAS:528:DyaF3cXitVOrsg%3D%3D]; Bibcode number [1959PhRvL...3...34M]Publisher Full Text
R.C.A. Review. 1975, 36:177.
COI number [1:CAS:528:DyaE2MXltVGlsrk%3D]
Appl. Phys. Lett.. 1975, 27:275.
COI number [1:CAS:528:DyaE2MXlsFKksr4%3D]; Bibcode number [1975ApPhL..27..275F]Publisher Full Text
Sol. Energy. 1998, 63:199-216.
COI number [1:CAS:528:DyaK1cXotV2gsb4%3D]Publisher Full Text
Mwakikunga BW, Sideras-Haddad E, Forbes A, Ray SS, Arendse C, Katumba G: Metal–to–insulator transitions and the thermochromism of VO2 at nanoscale in chromic materials, phenomena and their applications. Edited by Somani P. Applied Science Innovations Private Limited (ASIPL), Maharashtra, India; 2009. PubMed Abstract
J. Phys. Chem. Solids. 2007, 68:1821.
COI number [1:CAS:528:DC%2BD2sXhtFejt7rK]; Bibcode number [2007JPCS...68.1821S]Publisher Full Text
Solid State Sci.. 2006, 8:1168.
COI number [1:CAS:528:DC%2BD28XhtVOnur7P]; Bibcode number [2006SSSci...8.1168L]Publisher Full Text
Mater. Res. Bull.. 2007, 42:354.
COI number [1:CAS:528:DC%2BD2sXosFGktg%3D%3D]Publisher Full Text
Thin Solid Films. 1999, 352:107. Publisher Full Text
Physica Status Solidi (A) Appl. Mater.. 2008, 205(10):2409-2412.
COI number [1:CAS:528:DC%2BD1cXhtlajtbfM]Publisher Full Text
Appl. Phys. Lett.. 1996, 68(22):3081-3083.
COI number [1:CAS:528:DyaK28Xjt1ejs7g%3D]; Bibcode number [1996ApPhL..68.3081G]Publisher Full Text
Chem. Phys. Lett.. 2005, 413:88.
COI number [1:CAS:528:DC%2BD2MXps12qtbY%3D]; Bibcode number [2005CPL...413...88M]Publisher Full Text
Opt. Commun.. 2008, 281(24):6024-6027.
COI number [1:CAS:528:DC%2BD1cXhtlGjur%2FF]; Bibcode number [2008OptCo.281.6024B]Publisher Full Text
Optical Mater.. 2007, 29(5):481.
COI number [1:CAS:528:DC%2BD28Xht1elurnP]; Bibcode number [2007OptMa..29..481M]Publisher Full Text
J. Nanosci. Nanotechnol.. 2008, 9:3286. Publisher Full Text
Phys. Stat. Solidi (a). 2008, 205:150.
COI number [1:CAS:528:DC%2BD1cXhvFeiu7w%3D]Publisher Full Text
OAtube Nanotechnol. 2009, 2:109.
Nano Lett. 2009.
J. Am. Chem. Soc.. 2009, 131:12086.
COI number [1:CAS:528:DC%2BD1MXpsFyit7w%3D]PubMed Abstract | Publisher Full Text
Nanoscale Res. Lett.. 2009, 4:1335.
COI number [1:CAS:528:DC%2BD1MXhtlarsr3J]PubMed Abstract | Publisher Full Text | PubMed Central Full Text
Nanoscale Res. Lett.. 2007, 2:496.
COI number [1:CAS:528:DC%2BD2sXhtl2rtrvM]; Bibcode number [2007NRL.....2..496R]Publisher Full Text
Nanoscale Res. Lett.. 2007, 2:405.
COI number [1:CAS:528:DC%2BD2sXhtFGnt7fP]; Bibcode number [2007NRL.....2..405W]Publisher Full Text
Int. J. Nanoparticles. 2008, 1:3. Publisher Full Text
Nanoscale Res. Lett.. 2008, 3:372.
COI number [1:CAS:528:DC%2BD1cXhsVyhtrrE]; Bibcode number [2008NRL.....3..372M]Publisher Full Text
Nanoscale Res. Lett.. 2009, 4:565.
COI number [1:CAS:528:DC%2BD1MXmsFeht70%3D]; Bibcode number [2009NRL.....4..565W]PubMed Abstract | Publisher Full Text | PubMed Central Full Text
J. Phys. Chem.. 1976, 80:2728.
COI number [1:CAS:528:DyaE2sXhtVGqsg%3D%3D]Publisher Full Text
J. Am. Chem. Soc.. 1983, 105:2574.
COI number [1:CAS:528:DyaL3sXhs1OksbY%3D]Publisher Full Text
Langmuir. 1999, 15:83.
COI number [1:CAS:528:DyaK1cXnvValuro%3D]Publisher Full Text
J. Photochem.. 1974, 3:189.
COI number [1:CAS:528:DyaE2MXpvFCk]Publisher Full Text
J. Photochem. Photobiol. Chem.. 2008, 199:156.
COI number [1:CAS:528:DC%2BD1cXhtVGjtr7J]Publisher Full Text
Chem. Mater.. 2004, 16:963.
COI number [1:CAS:528:DC%2BD2cXhsFyhs7Y%3D]Publisher Full Text
Chem. Phys. Lett.. 2006, 428:426.
COI number [1:CAS:528:DC%2BD28XptVCgurk%3D]; Bibcode number [2006CPL...428..426I]Publisher Full Text
Chem. Mater.. 1991, 3:578.
COI number [1:CAS:528:DyaK3MXksFOktbk%3D]Publisher Full Text
Extremophiles. 2007, 11:445.
COI number [1:CAS:528:DC%2BD2sXltVGqsb8%3D]PubMed Abstract | Publisher Full Text
Phys. Rev. B. 2001, 64:075414.
Bibcode number [2001PhRvB..64g5414F]Publisher Full Text
Nature. 1992, 360:444.
COI number [1:CAS:528:DyaK3sXhtlyntb8%3D]; Bibcode number [1992Natur.360..444T]Publisher Full Text
Adv. Mater.. 2008, 20:2622.
COI number [1:CAS:528:DC%2BD1cXptVOrsLc%3D]; Bibcode number [2005JMatR..20.2622L]Publisher Full Text
J. Mater. Chem.. 2009, 19:6073.
COI number [1:CAS:528:DC%2BD1MXpvF2isLo%3D]Publisher Full Text
Catal. Today. 2003, 78:85.
COI number [1:CAS:528:DC%2BD3sXitFGqsbs%3D]Publisher Full Text
Solid State Commun.. 2003, 126:489.
COI number [1:CAS:528:DC%2BD3sXjsVaqtrs%3D]; Bibcode number [2003SSCom.126..489I]Publisher Full Text
J. Solid State Chem.. 1995, 120:137.
COI number [1:CAS:528:DyaK2MXpsFCnurg%3D]; Bibcode number [1995JSSCh.120..137R]Publisher Full Text