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Open Access Nano Express

Polymeric Nanocapsule from Silica Nanoparticle@Cross-linked Polymer Nanoparticles via One-Pot Approach

Ruoping Shen, Bin Mu, Pengcheng Du and Peng Liu*

Author affiliations

State Key Laboratory of Applied Organic Chemistry and Institute of Polymer Science and Engineering, College of Chemistry and Chemical Engineering, Lanzhou University, 730000, Lanzhou, People’s Republic of China

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Citation and License

Nanoscale Research Letters 2009, 4:1271-1274  doi:10.1007/s11671-009-9392-9

Published: 16 July 2009

Abstract

A facile strategy was developed here to prepare cross-linked polymeric nanocapsules (CP nanocapsules) with silica nanoparticles as templates. The silica nanoparticle@cross-linked polymer nanoparticles were prepared by the encapsulation of the silica nanoparticles by the one-pot approach via surface-initiated atom transfer radical polymerization of hydroxyethyl acrylate in the presence ofN,N′-methylenebisacrylamide as a cross-linker from the initiator-modified silica nanoparticles. After the silica nanoparticle templates were etched with hydrofluoric acid, the CP nanocapsules with particle size of about 100 nm were obtained. The strategy developed was confirmed with Fourier transform infrared, thermogravimetric analysis and transmission electron microscopy.

Keywords:
Polymeric nanocapsule; Cross-linked; Template; One-pot; SI-ATRP