Open Access Nano Express

Synthesis, Electrical Measurement, and Field Emission Properties of α-Fe2O3Nanowires

Li-Chieh Hsu1, Yuan-Yao Li1* and Chun-Yen Hsiao2

Author Affiliations

1 Department of Chemical Engineering, National Chung Cheng University, 168 University Rd, Min-Hsiung, Chia-Yi, 621, Taiwan, R.O.C

2 TECO Nanotech Co. Ltd, Taoyuan, 328, Taiwan, R.O.C

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Nanoscale Research Letters 2008, 3:330-337  doi:10.1007/s11671-008-9161-1


The electronic version of this article is the complete one and can be found online at:


Received:26 June 2008
Accepted:18 August 2008
Published:9 September 2008

© 2008 to the authors

Abstract

α-Fe2O3nanowires (NWs) were formed by the thermal oxidation of an iron film in air at 350 °C for 10 h. The rhombohedral structure of the α-Fe2O3NWs was grown vertically on the substrate with diameters of 8–25 nm and lengths of several hundred nm. It was found that the population density of the NWs per unit area (DNWs) can be varied by the film thickness. The thicker the iron film, the more NWs were grown. The growth mechanism of the NWs is suggested to be a combination effect of the thermal oxidation rate, defects on the film, and selective directional growth. The electrical resistivity of a single NW with a length of 800 nm and a diameter of 15 nm was measured to be 4.42 × 103 Ωcm using conductive atomic force microscopy. The field emission characteristics of the NWs were studied using a two-parallel-plate system. A low turn–on field of 3.3 V/μm and a large current density of 10−3 A/cm2(under an applied field of about 7 V/μm) can be obtained using optimal factors ofDNWsin the cathode.

Keywords:
Nanowires; Field emission; Conductive atomic force microscopy (CAFM)

Introduction

One-dimensional (1D) nanostructures have been extensively studied because of their unique chemical and physical characteristics. Because of their high aspect ratio and sharp tips that enhance the local electrical field, they can be used as emitters in field emission (FE) applications [1]. Factors that affect FE properties include the population density of the emitters (the number of emitters per unit square) [2], the electronic resistance of a single emitter [3], and the aspect ratio (radius and length) [4]. The field emission properties of an emitter are affected by nearby emitters, which is called the field screen effect. Many research groups have studied the relationship between FE properties (field screen effect) and the population density of emitters for ZnO nanowires (NWs) [5], Si NWs [6], CNTs [2,3], and CuO NWs [1]. Poor FE properties were obtained when the population density of the emitters was too high.

Investigating the electronic properties of 1D nanomaterials can reveal the relationship between the electronic properties of emitters and the FE properties of the device. In addition, it can provide useful information for the theoretical study of FE characteristics. Electronic measurement methods for NWs are generally categorized into four types: (1) laterally growing NWs between two electrodes and directly measuring them [7,8], (2) spreading the NWs on a large number of patterned electrodes and measuring a single NW on a pair of electrodes [9,10], (3) directly measuring vertical NWs using conductive atomic force microscopy (CAFM) [11,12], and (4) measuring aligned NWs arrays using two electrode films [13,14]. The CAFM system is a convenient method for the non-destructive characterization of the electronic properties of NWs.

α-Fe2O3 (hematite) is a semiconductor (Eg = 2.1 eV) and the most stable iron oxide under an ambient environment [15]. α-Fe2O3 NWs have recently been synthesized by various research groups [16,17]. Because they are thermally stable, resistant to oxidation, and have a high aspect ratio, α-Fe2O3 NWs are a candidate emitters for FE applications. It has been reported that an electrical field of 7–8 V/μm is required to obtain a 10−5 A/cm2 emission current using densely packed α-Fe2O3 NWs as emitters [16]. However, there have been no detailed studies on FE properties related to the population density of α-Fe2O3 NWs (DNWs) and their resistance (RNW).

In this study, we report a simple method that can be used to control the population density of α-Fe2O3NWs (DNWs) by varying the film thickness of iron. The FE properties of α-Fe2O3NWs with various population densities and resistances (RNW) were studied. It was found that the best FE properties can be obtained by using the optimalDNWsin the cathode.

Experimental Details

α–Fe2O3NWs were grown using an iron film thermally oxidized at 350 °C for 10 h. Iron films with thicknesses of 30 nm, 50 nm, 100 nm, and 150 nm were coated on indium tin oxide (ITO) glass by direct current (DC) sputtering. The iron-coated substrates were heated at 350 °C for 10 h in an oven in the air atmosphere. The morphology and crystalline structure of the as-synthesized NWs were characterized by field emission scanning electron microscopy (FE-SEM, HITACH S-4800) and high-resolution transmission electron microscopy (HR-TEM, JEOL JSM 3010), respectively. The current–voltage (I–V) characteristics of the as-grown NWs were obtained using the CAFM (SEIKO SPA-400) system. A highly conductive polygon shaped tip with a height of 10 μm and a radius of 50 nm (the top of the tip) was used as an electronic probe while ITO was used as an electrode. The applied voltages were −10 V to +10 V. FE properties were measured in a vacuum chamber at 6 × 10−6 torr. The sweep voltage was 0–1100 V and the emission current was measured using Keithley 2410.

Results and Discussion

Figure 1a and b shows the top view and cross-section view of the Fe-coated (50 nm) ITO glass after thermal oxidation at 350 °C for 10 h, respectively. As can be seen in Fig. 1a, the NWs formed randomly on the film. Figure 1b shows that the NWs were grown vertically on the film with diameters of 8–25 nm and lengths of several hundred nm. Fe film was oxidized during the process and became α-Fe2O3film with a thickness of 100 nm.

thumbnailFigure 1. FE-SEM images of (a) the top view and (b) cross-section view of NWs synthesized on Fe-coated (50 nm) ITO glass at 350 °C for 10 h

Figure 2 shows the TEM images of an α-Fe2O3 NW which was grown on the iron film with a thickness of 50 nm. As can be seen in Fig. 2a, the length and diameter of the as-produced α-Fe2O3NWs were approximately 240 nm and 25 nm, respectively. Figure 2b shows the high-resolution TEM image and its corresponding selective area electron diffraction (SAED) pattern (inset). It was found that the NW is a single crystalline α-Fe2O3NW with the [110] growth direction. The interplanar spacing of 0.251 nm agrees well with the fringe spacing of α-Fe2O3. The SAED pattern reveals that the crystal structure of the α-Fe2O3NW is rhombohedral.

thumbnailFigure 2. (a) TEM image of an α-Fe2O3NW, (b) HR-TEM image of the α-Fe2O3 nanowire, and the SAED pattern of the α-Fe2O3 NW (inset)

The length, diameter, and population density of the α-Fe2O3NWs were studied for various Fe film thicknesses. Samples A, B, C, and D represent the materials after the thermal oxidation of the 30 nm, 50 nm, 100 nm, and 150 nm-thick iron films, respectively. Figure 3a–d shows the top views of sample A (30 nm), sample B (50 nm), sample C (100 nm), and sample D (150 nm), respectively. As can be seen, the number of α-Fe2O3NWs increased with an increase of the film thickness.DNWswas calculated from the SEM image as 1.6 × 108 NWs/cm2for sample A, 7.8 × 108 NWs/cm2for sample B, 13.2 × 108 NWs/cm2for sample C, and 18.3 × 108 NWs/cm2for sample D. Table 1summarizes the population densities of the samples. Figure 3e shows a plot of NW density (DNWs) versus iron film thickness. The error in theDNWsmeasurements is about 5%.

thumbnailFigure 3. FE-SEM images of α-Fe2O3 NWs grown on (a) 30 nm, (b) 50 nm, (c) 100 nm, and (d) 150 nm iron films, and (e) the population density of α-Fe2O3 NWs as a function of the film thickness

Table 1. Summary of the population densities (DNWs), resistances of NWs (RNW), turn–on field (Eto), and calculated field enhancement factors (β) for samples A, B, C, and D

The growth mechanism of the α-Fe2O3 NWs via thermal oxidation was discussed by Takagi [18] and Fu et al. [19]. They proposed that the growth mechanism of the α-Fe2O3 NWs was neither vapor–liquid–solid (VLS) nor vapor–solid (VS). A tip growth mechanism was suggested, in which the NWs are grown by the diffusion of oxygen atoms on the surface defects of the iron film. During the thermal process, the oxygen molecules diffuse into the iron film between the iron atoms and form Fe–O bonds. The process involves a volume expansion in all three dimensions to accommodate the oxygen atoms. However, because the iron film prevents expansion in the two lateral directions, the volume of oxides expands upward only. A thin oxide film is therefore formed on the substrate. While a layer of the oxide forms, defects are created in the oxide film. This might be caused by a rapid thermal oxidation rate on the surface of the film during the temperature ramping period. The defects can be seen as crackings on the surface of the film (Fig. 1a). As the oxidation time increases, in regions with a higher degree of defects, the oxygen molecules move faster, diffuse across the existing oxide layer, and react with iron to form iron oxide. There was an oxidation rate difference (growth rate of α-Fe2O3 NWs) between the high degree and low degree defect regions. In addition, the preferred growth orientation of α-Fe2O3 NWs was the [110] direction (Fig. 2b), which suggests that the fastest growth rate was along the [110] direction. Therefore, the oxidation rate difference and the selective directional growth are probable reasons for the formation of α-Fe2O3 NWs. A schematic graph of the formation of α-Fe2O3 NWs is shown in Fig. 4. Samples I and II represent the thin and thick iron films, respectively. After oxidation for a period of time (stage A), the thin iron film (sample I) was completely oxidized to become α-Fe2O3 NWs and α-Fe2O3 film. In contrast, the thick iron film was partially oxidized so that α-Fe2O3 NWs, α-Fe2O3 film, and Fe film were present in stage I. At this stage, for both samples I and II, short NWs (<100 nm) and long NWs (>500 nm) grew from the low and high degree defect regions of the film, respectively. As the oxidation time increased (stage B), the length and DNWs of sample I did not change because the oxidation terminated at stage A. For sample II, the oxidation continued; NWs were continuously grown, becoming longer and more dense. Takagi [18] observed that the population density and the length of NWs were dependent of the oxidation time. Our results show good agreement with Takagi’s report. The population density of NWs can be increased by increasing the thickness of the iron film.

thumbnailFigure 4. A schematic graph of the formation of the α-Fe2O3 NWs in thin and thick iron

CAFM was employed to measure the electronic property of a single α-Fe2O3NW and α-Fe2O3film. Figure 5a shows the schematic drawing of the CAFM measurement. NWs were embedded in photoresist (PR) and only the tips of the NWs (sample B) were exposed. The CAFM tip made contact with the exposed tips of the NWs so that their electronic properties could be measured. Using PR prevented the bending of the NWs while the CAFM tip approached them. The applied voltage was swept from −10 V to +10 V to obtain the I–V characteristics for a single NW. The equivalent circuit diagram for the measurement of an α-Fe2O3NW is shown in Fig. 5b.Rcontactis the contact resistance between the CAFM tip and the NW.RNWandRfilmare the resistances of the NW and the film, respectively. The overall resistance (Roverall) is the sum ofRcontact,RNW, andRfilm. It can be expressed as:

(1)

thumbnailFigure 5. (a) Schematic illustration and (b) circuit diagram of conductive atomic force microscopy. (c) Top-view and side-view (inset) FE-SEM images of the embedded NWs

Figure 5c shows the top view and side view (inset) of a sample. As can be seen, a single NW with a diameter of 15 nm and a length of 800 nm was embedded in the PR. Only the tip of the NW was exposed on the PR surface. The figure also shows that the NWs were not bent or damaged after the spin coating process of the PR. Figure 6a and b shows the morphology image and current image, respectively, taken at a +10 V bias on a single NW. The tip used for CAFM was an Au-coated silicon tip, with a diameter of about 50 nm. The morphology image of the NW shows that the diameter of the NW was larger than that observed by SEM, which was due to the large diameter of the scanning tip. From the current image taken at a +10 V bias, the bright zone indicates that a current appeared on the tip of the single NW. It can also be seen that there was no current signal in the PR region. Figure 7 shows the I–V curves of the structure of the ITO/α-Fe2O3film/α-Fe2O3NW/CAFM-tip (Fig. 7a) and the ITO/α-Fe2O3film/ CAFM-tip (Fig. 7b). Nanowires from sample B were removed by ultrasonication in ethanol. The bias voltage was swept from −10 V to +10 V. The measured resistances of the ITO/α-Fe2O3film/α-Fe2O3NW/CAFM-tip structure (Roverall) and the ITO/α-Fe2O3film/CAFM-tip structure (indicated asRfilm + Rcontact) were 2 × 1011 Ω and 4.2 × 109 Ω, respectively. BecauseRfilm + Rcontact(4.2 × 109 Ω) was much smaller thanRoverall(2 × 1011 Ω) andRcontactis considered to be much smaller thanRNWandRfilm, Eq. 1can be rewritten as:

(2)

thumbnailFigure 6. The CAFM images of (a) morphology and (b) current taken at a +10 V bias

thumbnailFigure 7. The I–V characteristics of (a) the ITO/α-Fe2O3 film/α-Fe2O3 NW/CAFM-tip structure and (b) the ITO/α-Fe2O3 film /CAFM-tip structure

In other words, the resistance of the ITO/α-Fe2O3film/α-Fe2O3NW/CAFM-tip structure (Roverall) can be considered asRNW.RNWcan be expressed as:

(3)

where ρ is the electronic resistivity of an α-Fe2O3NW, andLandrrepresent the average length (800 nm) and radius (15 nm) of the NW, respectively. We assumed that ρ (4.42 × 103 Ωcm) is a constant for all of the as-produced α-Fe2O3NWs. Using the mean length and radius of the NWs,RNW(orRoverall) of samples A, B, C, and D was calculated as 1.25 × 1011, 1.4 × 1011, 1.4 × 1011, and 6.25 × 1010 Ω, respectively. The values are shown in Table 1.

The two-parallel-plate system used for FE measurement is shown in Fig. 8a. The cathode consisted of the α-Fe2O3 emitters, α-Fe2O3 film, and ITO glass while the anode was ITO glass. The cathode and anode were separated by a 150 μm-thick spacer. Figure 8b shows the curve of the field emission current density versus electrical field (J-E) for the four samples. The turn-on field (Eto) is defined as the value of the applied electrical field which produces an emission current density of 10 μA/cm2. To analyze the field emission properties of α-Fe2O3 NWs, the Fowler-Nordheim (F-N) [20] equation was used. The equation can be expressed as:

(4)

where J is the emission current density; φ is the work function; F is the electrical field; A = 1.54 × 10−6 AeVV−2; B = 6.83 × 103 eV−3/2 Vμm−1, and β is the field enhancement factor. β is a parameter that depends on the crystal structure and the morphology of the emitters. The work function of α-Fe2O3 is 5.6 eV [16], so β can be calculated as 1023, 1754, 1434, and 1420 for samples A, B, C, and D, respectively. Figure 8c shows the Fowler-Nordheim (F-N) plot of the four samples. The linear relationship of 1/E and ln(J/E2) indicates that the field emission behavior of the samples fits the F-N mechanism. Table 1 summarizes the results of the turn-on field and field enhancement factor (β). Emitters with DNWs of 7.8 × 108 NWs/cm2 (sample B) showed the lowest Eto and the highest β in our study. Sample B had a medium population density of the α-Fe2O3 emitters. In contrast, emitters with low DNWs (sample A) showed the lowest β and a “modest” Eto due to insufficient emission sites.[3] Densely packed NWs (samples C and D) caused the screen effect[21], leading to field emission performance that was not as good as that of sample B. Compared to other 1D materials, such as ZnO NWs, [5] Si NWs, [6] CNTs [2,3], and CuO NWs, [1] NWs with high β and low Eto can be achieved by controlling their population density. Our study agrees well with other studies.

thumbnailFigure 8. (a) Illustration of the two-parallel-plate configuration used for field emission (FE) measurement, (b) the current density as a function of the electrical field for the four samples, and (c) the F–N plot

The relationship between the field enhancement factor (β), resistance of α-Fe2O3 NWs (RNW), and the population density (DNWs) of the four samples was analyzed; it is shown in Fig. 9. RNW of samples A, B, C, and D are similar, but β is different for each sample. According to the results, the value of β depends on DNW more than it does on RNW. Bonard et al. [21] observed that β depends on DNW more than it does on the length of CNT. The length of CNT increased with an increase in resistance. Our results show good agreement with Bonard’s research.

thumbnailFigure 9. The field enhancement factor (β) and resistance of NWs (RNW) as a function of the turn-on field (Eto)

Conclusion

The formation, electronic characterization, and field emission application of α-Fe2O3NWs were studied. α-Fe2O3NWs were grown vertically on the substrate via the thermal oxidation of an iron film in air at 350 °C for 10 h. By increasing the film thickness (to 30, 50, 100, and 150 nm),DNWscould be increased.RNWof the NWs was estimated using the CAFM technique. In the FE study, anEtoof 3.3 V/μm and a large current density of 10−3 A/cm2(under an applied field of about 7 V/μm) were obtained with the optimumDNWs. The densely packed NWs caused the screen effect, leading to poor FE performance. The field enhancement factor (β) depends onDNWmore than it does onRNW. This study shows that α-Fe2O3NWs are a candidate for emitters in field emission applications.

Acknowledgments

The authors would like to thank Mr. Shu-Teng Chou at Advantage Scientific Incorporated for his help in CAFM measurements. Mr. Chien-Wei Huang at National Chung Cheng University is acknowledged for his help in sputtering iron films.

References

  1. Zhu YW, Yu T, Cheong FC, Xui XJ, Lim CT, Tan VBC, et al.: Large-scale synthesis and field emission properties of vertically oriented CuO nanowire films.

    Nanotechnology 2005, 16:88-92.

    COI number [1:CAS:528:DC%2BD2MXitVaksLk%3D]

    Publisher Full Text OpenURL

  2. Nilsson L, Groening O, Emmenegger C, Kuettel O, Schaller E, Schlapbach L, et al.: Scanning field emission from patterned carbon nanotube films.

    Appl. Phys. Lett. 2000, 76:2071-2073.

    COI number [1:CAS:528:DC%2BD3cXitlSrsr0%3D]

    Publisher Full Text OpenURL

  3. Gao H, Mu C, Wang F, Xu DS, Wu K, Xie YC, et al.: Field emission of large-area and graphitized carbon nanotube array on anodic aluminum oxide template.

    J. Appl. Phys. 2003, 93:5602-5605.

    COI number [1:CAS:528:DC%2BD3sXjtVyisrk%3D]

    Publisher Full Text OpenURL

  4. Bonard JM, Croci M, Arfaoui I, Noury O, Sarangi D, Chatelain A: Can we reliably estimate the emission field and field enhancement factor of carbon nanotube film field emitters?

    Diam. Relat. Mater. 2002, 11:763-768.

    COI number [1:CAS:528:DC%2BD38XjvVenur4%3D]

    Publisher Full Text OpenURL

  5. Jo SH, Lao JY, Ren ZF, Farrer RA, Baldacchini T, Fourkas JT: Field-emission studies on thin films of zinc oxide nanowires.

    Appl. Phys. Lett. 2003, 83:4821-4823.

    COI number [1:CAS:528:DC%2BD3sXps1Wmtrg%3D]

    Publisher Full Text OpenURL

  6. Zeng BQ, Xiong GY, Chen S, Wang WZ, Wang DZ, Ren ZF: Field emission of silicon nanowires grown on carbon cloth.

    Appl. Phys. Lett. 2007, 90:033112-1-033112-3. OpenURL

  7. Kim J, Anderson WA: Direct electrical measurement of the self-assembled nickel silicide nanowire.

    Nano Lett. 2006, 6:1356-1359.

    COI number [1:CAS:528:DC%2BD28Xlt1yqsrs%3D]

    Publisher Full Text OpenURL

  8. Lee JS, Islam MS, Kim S: Direct formation of catalyst-free ZnO nanobridge devices on an etched Si substrate using a thermal evaporation method.

    Nano Lett. 2006, 6:1487-1490.

    COI number [1:CAS:528:DC%2BD28XlsFarurY%3D]

    Publisher Full Text OpenURL

  9. Hernandez-Ramirez F, Tarancon A, Casals O, Pellicer E, Rodriguez J, Romano-Rodriguez A, et al.: Electrical properties of individual tin oxide nanowires contacted to platinum electrodes.

    Phys. Rev. B 2007, 76:085429-085433. Publisher Full Text OpenURL

  10. Seong HK, Kim JY, Kim JJ, Lee SC, Kim SR, Kim U, et al.: Room-temperature ferromagnetism in cu doped GaN nanomores.

    Nano Lett. 2007, 7:3366-3371.

    COI number [1:CAS:528:DC%2BD2sXhtFSjt7nL]

    Publisher Full Text OpenURL

  11. Nebeschutz M, Cimalla V, Ambacher O, Machleidt T, Ristic J, Calleja E: Electrical performance of gallium nitride nanocolumns.

    Physica E 2007, 37:200-203. Publisher Full Text OpenURL

  12. Schlenker E, Bakin A, Postels B, Mofor AC, Wehmann HH, Weimann T, et al.: Electrical characterization of ZnO nanorods.

    Physica E 2007, 244:1473-1477.

    COI number [1:CAS:528:DC%2BD2sXht1CrsbfI]

    OpenURL

  13. Adeyeye AO, White RL: Magnetoresistance behavior of single castellated Ni80Fe20 nanowires.

    J. Appl. Phys. 2004, 95:2025-2028.

    COI number [1:CAS:528:DC%2BD2cXosVyjtQ%3D%3D]

    Publisher Full Text OpenURL

  14. Liu I, Wu YH, Long HH, Liu ZJ, Zheng YK, Adeyeye AO: Transport properties and micromagnetic modeling of magnetic nanowires with multiple constrictions.

    Thin Solid Films 2006, 505:35-40.

    COI number [1:CAS:528:DC%2BD28XisF2jtbY%3D]

    Publisher Full Text OpenURL

  15. Dieckmann R: Point-defects and transport in hematite (Fe2o3-Epsilon).

    Philos. Mag. A 1993, 68:725-745.

    COI number [1:CAS:528:DyaK3sXmvVejtLo%3D]

    Publisher Full Text OpenURL

  16. Chueh YL, Lai MW, Liang JQ, Chou LJ, Wang ZL: Systematic study of the growth of aligned arrays of alpha-Fe2O3 and Fe3O4 nanowires by a vapor-solid process.

    Adv. Funct. Mater. 2006, 16:2243-2251.

    COI number [1:CAS:528:DC%2BD28Xht1Onsr%2FO]

    Publisher Full Text OpenURL

  17. Takagi R:

    J. Phys. Soc. Jpn.. 1957, 12:1212-1218.

    COI number [1:CAS:528:DyaG1cXhsFamsw%3D%3D]

    Publisher Full Text OpenURL

  18. Fu YY, Wang RM, Xu J, Chen J, Yan Y, Narlikar A, et al.: Synthesis of large arrays of aligned alpha-Fe2O3 nanowires.

    Chem. Phys. Lett. 2003, 379:373-379.

    COI number [1:CAS:528:DC%2BD3sXnsVelur0%3D]

    Publisher Full Text OpenURL

  19. Burgess RE, Kroemer H, Houston JM: Corrected values of Fowler-Nordheim field emission functions V(Y) and S(Y).

    Phys. Rev. 1953, 90:515-515. Publisher Full Text OpenURL

  20. Bonard JM, Weiss N, Kind H, Stockli T, Forro L, Kern K, et al.: Tuning the field emission properties of patterned carbon nanotube films.

    Adv. Mater. 2001, 13:184-188.

    COI number [1:CAS:528:DC%2BD3MXhs12qu74%3D]

    Publisher Full Text OpenURL