Open Access Nano Express

Enhancement of Sm3+emission by SnO2nanocrystals in the silica matrix

Jin Mu*, Lingyun Liu and Shi-Zhao Kang

Author Affiliations

Department of Chemistry, Key Laboratory for Ultrafine Materials of Ministry of Education, East China University of Science and Technology, 130 Meilong Road, Shanghai, 200237, China

For all author emails, please log on.

Nanoscale Research Letters 2007, 2:100-103  doi:10.1007/s11671-006-9037-1

Published: 17 January 2007

Abstract

Silica xerogels containing Sm3+ions and SnO2nanocrystals were prepared in a sol–gel process. The image of transmission electron microscopy (TEM) shows that the SnO2nanocrystals are dispersed in the silica matrix. The X-ray diffraction (XRD) of the sample confirms the tetragonal phase of SnO2. The xerogels containing SnO2nanocrystals and Sm3+ions display the characteristic emission of Sm3+ions (4G5/2 6HJ(J = 5/2, 7/2, 9/2)) at the excitation of 335 nm which energy corresponds to the energy gap of the SnO2nanocrystals, while no emission of Sm3+ions can be observed for the samples containing Sm3+ions. The enhancement of the Sm3+emission is probably due to the energy transfer from SnO2nanocrystals to Sm3+ions.

Keywords:
Sm3+ions; Emission; Sensibilization; SnO2nanocrystals; Silica matrix