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Open Access Nano Express

A solution blending route to ethylene propylene diene terpolymer/layered double hydroxide nanocomposites

H Acharya1, SK Srivastava1* and Anil K Bhowmick2

Author Affiliations

1 Department of Chemistry, Indian Institute of Technology, Kharagpur, West Bengal, 721302, India

2 Rubber Technology Centre, Indian Institute of Technology, Kharagpur, 721302, India

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Nanoscale Research Letters 2006, 2:1-5  doi:10.1007/s11671-006-9020-x


The electronic version of this article is the complete one and can be found online at:


Received:19 June 2006
Accepted:16 September 2006
Published:27 October 2006

© 2006 to the authors

Abstract

Ethylene propylene diene terpolymer (EPDM)/MgAl layered double hydroxide (LDH) nanocomposites have been synthesized by solution intercalation using organically modified LDH (DS-LDH). The molecular level dispersion of LDH nanolayers has been verified by the disappearance of basal XRD peak of DS-LDH in the composites. The internal structures, of the nanocomposite with the dispersion nature of LDH particles in EPDM matrix have been studied by TEM and AFM. Thermogravimetric analysis (TGA) shows thermal stability of nanocomposites improved by ≈40 °C when 10% weight loss was selected as point of comparison. The degradation for pure EPDM is faster above 380 °C while in case of its nanocomposites, it is much slower.

Keywords:
Layered double hydroxide; Nanocomposites; Solution blending

Nano Express

[1-19]

Acknowledgments

The authors are grateful to Ministry of Human Research and Development (MHRD), India for the financial support.

References

  1. Cavani F, Trifiro’ F, Vaccari A:

    Catal. Today. 1991, 11:197. Publisher Full Text OpenURL

  2. Leroux F, Besse J:

    Chem. Mater.. 2001, 13:3507.

    COI number [1:CAS:528:DC%2BD3MXmvVKjtr0%3D]

    Publisher Full Text OpenURL

  3. Newman SP, Jones W:

    New. J. Chem.. 1998, 22:105.

    COI number [1:CAS:528:DyaK1cXhslait7g%3D]

    Publisher Full Text OpenURL

  4. Meneghetti P, Qutubuddin S:

    Thermochim. Acta. 2006, 442:74.

    COI number [1:CAS:528:DC%2BD28XisFOmurs%3D]

    Publisher Full Text OpenURL

  5. Wang GA, Wang CC, Chen CY:

    Polymer. 2005, 46:5065.

    COI number [1:CAS:528:DC%2BD2MXltFSltb0%3D]

    Publisher Full Text OpenURL

  6. Srivastava SK, Pramanik M, Acharya H:

    J. Polym. Sci. Part B: Polym. Phys.. 2006, 44:471.

    COI number [1:CAS:528:DC%2BD28XotFWqsA%3D%3D]

    Publisher Full Text OpenURL

  7. Wang D, Wilkie CA:

    J. Vinyl Additive Technol.. 2004, 8:238. Publisher Full Text OpenURL

  8. Liu ZH, Yang XY, Makita Y, Ooi K:

    Chem. Mater.. 2002, 14:4800.

    COI number [1:CAS:528:DC%2BD38XotVegtbk%3D]

    Publisher Full Text OpenURL

  9. Usuki A, Tukigase A, Kato M:

    Polymer. 2002, 43:2185.

    COI number [1:CAS:528:DC%2BD38XhtFGrs78%3D]

    Publisher Full Text OpenURL

  10. Acharya H, Pramanik M, Srivastava SK, Bhowmick AK:

    J. Appl. Polym. Sci.. 2004, 93:2429.

    COI number [1:CAS:528:DC%2BD2cXmtlGhsb0%3D]

    Publisher Full Text OpenURL

  11. Sundell S:

    Acta Chem. Scand. A. 1977, 31:799. Publisher Full Text OpenURL

  12. Wilson OC, Olorunyolemi T, Jaworski A, Borum L, Young D, Siriwat A, Dickens E, Oriakhi C, Lerner M:

    Appl. Clay Sci.. 1999, 15:265.

    COI number [1:CAS:528:DyaK1MXkvVersbs%3D]

    Publisher Full Text OpenURL

  13. Costa FR, Abdel-Goad M, Wagenknecht U, Heinrich G:

    Polymer. 2005, 46:4447.

    COI number [1:CAS:528:DC%2BD2MXktlCgtr0%3D]

    Publisher Full Text OpenURL

  14. Chen W, Feng L, Qu B:

    Chem. Mater.. 2004, 16:368.

    COI number [1:CAS:528:DC%2BD2cXksFCgug%3D%3D]

    Publisher Full Text OpenURL

  15. Lee WD, Im SS, Lim HM, Kim KJ:

    Polymer. 2006, 47:1364.

    COI number [1:CAS:528:DC%2BD28Xht1Gjt7o%3D]

    Publisher Full Text OpenURL